Citation: Ming-Xian Liu, Ling-Yan Chen, Da-Zhang Zhu, Hui Duan, Wei Xiong, Zi-Jie Xu, Li-Hua Gan, Long-Wu Chen. Zinc tartrate oriented hydrothermal synthesis of microporous carbons for high performance supercapacitor electrodes[J]. Chinese Chemical Letters, ;2016, 27(03): 399-404. doi: 10.1016/j.cclet.2015.12.026 shu

Zinc tartrate oriented hydrothermal synthesis of microporous carbons for high performance supercapacitor electrodes

a.
a. Shanghai Key Lab of Chemical Assessment and Sustainability, Department of Chemistry, Tongji University, Shanghai 200092, China;
b.
b. School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430073, China

Corresponding author: Li-Hua Gan,
Received Date: 28 September 2015
Available Online: 21 December 2015
Fund Project: This work was financially supported by the National Natural Science Foundation of China (Nos.21207099, 21273162, 21473122) (Nos.21207099, 21273162, 21473122) the Fundamental Research Funds for the Central Universities, and the Large Equipment Test Foundation of Tongji University. (No.14DZ2261100)

A novel zinc tartrate oriented hydrothermal synthesis of microporous carbons was reported. Zinc-organic complex obtained via a simple chelation reaction of zinc ions and tartaric acid is introduced into the networks of resorcinol/formaldehyde polymer under hydrothermal condition. After carbonization process, the resultant microporous carbons achieve high surface area (up to 1255 m²/g) and large mean pore size (1.99 nm) which guarantee both high specific capacitance (225 F/g at 1.0 A/g) and fast charge/discharge operation (20 A/g) when used as a supercapacitor electrode. Besides, the carbon electrode shows good cycling stability, with 93% capacitance retention at 1.0 A/g after 1000 cycles. The welldesigned and high-performance microporous carbons provide important prospects for supercapacitor applications.
- Zinc tartrate,
- Hydrothermal synthesis,
- Microporous carbon,
- Supercapacitor,
- Electrode
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