Citation: Xu Ming-Kun, Ouyang Zhen-Hua, Shen Zhu-Rui. Topological evolution of cerium (Ⅲ) molybdate microflake assemblies induced by amino acids[J]. Chinese Chemical Letters, ;2016, 27(5): 673-677. doi: 10.1016/j.cclet.2015.12.023 shu

Topological evolution of cerium (Ⅲ) molybdate microflake assemblies induced by amino acids

a.
Key Laboratory of Advanced Ceramics and Machining Technology, Ministry of Education, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China
b.
Institute of New Catalytic Materials Science, Key Laboratory of Advanced Energy Materials Chemistry Ministry of Education, College of Chemistry, Nankai University, Tianjin 300071, China
c.
Jiangsu Province Key Laboratory of Fine Petrochemical Engineering, Changzhou University, Changzhou 213164, China

Corresponding author: Shen Zhu-Rui, shenzhurui@tju.edu.cn
Received Date: 21 October 2015
Revised Date: 15 December 2015
Accepted Date: 23 December 2015
Available Online: 6 May 2016

Figures(4)

In this work, cerium(Ⅲ) molybdate microspheres configured as microflakes were synthesized in the presence of lysine via a hydrothermal process. We studied the role of lysine and other amino acids on the morphologic control of cerium(Ⅲ) molybdate crystals. First, with the increase of lysine, thinner microflakes and smaller microspheres are obtained. Moreover, a transformation in topology of cerium(Ⅲ) molybdate assemblies from three-dimensional (3D) into two-dimensional (2D) can be ascribed to controlled nucleation and growth of cerium(Ⅲ) molybdate induced by lysine. Second, amino acids with strong hydrophilic "R" groups tend to induce nucleation and result in spherical assemblies formed by nanoparticles or nanoflakes, while those with weaker hydrophilic "R" groups tend to induce growth and yield spherical assemblies of microflakes.
- Hydrothermal,
- Amino acids,
- Self-assembly,
- Cerium molybdate,
- Morphology control
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