Citation: Viran P. Mahida, Manish P. Patel. Superabsorbent amphoteric nanohydrogels:Synthesis, characterization and dyes adsorption studies[J]. Chinese Chemical Letters, ;2016, 27(03): 471-474. doi: 10.1016/j.cclet.2015.12.015 shu

Superabsorbent amphoteric nanohydrogels:Synthesis, characterization and dyes adsorption studies

  • Corresponding author: Manish P. Patel, 
  • Received Date: 13 May 2015
    Available Online: 21 September 2015

    Fund Project: This work was provided by University Grants Commission, New Delhi (No.F.39-685/2010(SR)) (No.F.39-685/2010(SR)

  • The goal of the present research is to remove high percentage of cationic and anionic dyes such as, Neutral Red, Safranin O and Indigo Carmine from aqueous solutions by poly(NIPAAm/N,N-diallylpyrrolidinium bromide/AA) superabsorbent amphoteric nanohydrogels synthesized using the inverse microemulsion polymerization method. Effect of various parameters such as, treatment time, initial dye concentration, pH and adsorbent dose were investigated. Furthermore, kinetics and isotherms adsorption models were applied to determine the maximum adsorption and mechanism for adsorption, which shows that adsorption obeyed the pseudo-second order kinetics. Fromthe results, removal of dyes within the nanohydrogel was found to be in the order:AB-74< BR-2 ≤BR-5.
  • 加载中
    1. [1]

      [1] L.L. Fan, Y. Zhang, X.J. Li, et al., Removal of alizarin red from water environment using magnetic chitosan with Alizarin Red as imprinted molecules, Colloids Surf., B:Biointerfaces 91(2012) 250-257.

    2. [2]

      [2] (Ⅰ). Ali, M. Asim, T.A. Khan, Low cost adsorbents for the removal of organic pollutants from wastewater, J. Environ. Manage. 113(2012) 170-183.

    3. [3]

      [3] M.A.M. Salleh, D.K. Mahmoud, W.A.W.A. Karim, A. (Ⅰ)dris, Cationic and anionic dye adsorption by agricultural solid wastes:a comprehensive review, Desalination 280(2011) 1-13.

    4. [4]

      [4] Y.J. Tang, X. Wang, L.H. Zhu, et al., Removal of methyl orange from aqueous solutions with poly(acrylic acid-co-acrylamide) superabsorbent resin, Polym. Bull. 70(2013) 905-918.

    5. [5]

      [5] H. Yao, X.M. You, Q. Lin, et al., Multi-stimuli responsive metal-organic gel of benzimidazol-based ligands with lead nitrate and their use in removal of dyes from waste-water, Chin. Chem. Lett. 24(2013) 703-706.

    6. [6]

      [6] S. Gokturk, S. Kaluc, Removal of selected organic compounds in aqueous solutions by activated carbon, J. Environ. Sci. Technol. 1(2008) 111-123.

    7. [7]

      [7] J. Zhang, Q.Q. Shi, C.L. Zhang, et al., Adsorption of Neutral Red onto Mn-impregnated activated carbons prepared from Typha orientalis, Bioresour. Technol. 99(2008) 8974-8980.

    8. [8]

      [8] E. Karadağ, O.B. Üzüm, A study on water and dye sorption capacities of novel ternary acrylamide/sodium acrylate/PEG semi (Ⅰ)PN hydrogels, Polym. Bull. 68(2012) 1357-1368.

    9. [9]

      [9] E. Karadağ, B. Hasgül, S. Kundakci, O.B. Uzum, et al., Montmorillonite loaded highly swollen AAm/AMPS hydrogels and semi-(Ⅰ)PNs with PEG as a novel composite polymeric sorbent for water and dye sorption, Polym.Plast. Technol. Eng. 53(2014) 1259-1271.

    10. [10]

      [10] J.J. Wang, F. Liu, Enhanced adsorption of heavy metal ions onto simultaneous interpenetrating polymer network hydrogels synthesized by UV irradiation, Polym. Bull. 70(2013) 1415-1430.

    11. [11]

      [11] Y.N. Patel, M.P. Patel, A new fast swelling poly[DAPB-co-DMAAm-co-AASS] superabsorbent hydrogel for removal of anionic dyes from water, Chin. Chem. Lett. 24(2013) 1005-1007.

    12. [12]

      [12] F.M.Pavel,Microemulsionpolymerization, J. DispersionSci.Technol.25(2004)1-16.

    13. [13]

      [13] N. Sahiner, Hydrogel nanonetworks with functional core-shell structure, Eur. Polym. J. 43(2007) 1709-1717.

    14. [14]

      [14] P.V. Dadhaniya, M.P. Patel, R.G. Patel, Removal of anionic dyes from aqueous solution using poly[N-vinyl pyrrolidone/2-(methacryloyloxyethyl) trimethyl ammonium chloride] superswelling hydrogels, Polym. Bull. 58(2007) 359-369.

    15. [15]

      [15] M. Kaplan, H. Kasgoz, Hydrogel nanocomposite sorbents for removal of basic dyes, Polym. Bull. 67(2011) 1153-1168.

    16. [16]

      [16] P.V. Dadhaniya, M.P. Patel, R.G. Patel, Swelling and dye adsorption study of novel superswelling[Acrylamide/N-vinylpyrrolidone/3(2-hydroxyethyl carbamoyl) acrylic acid] hydrogels, Polym. Bull. 57(2006) 21-31.

    17. [17]

      [17] V.P. Mahida, M.P. Patel, Synthesis of new superabsorbent poly(N(Ⅰ)PAAm/AA/Nallylisatin) nanohydrogel for effective removal of As(V) and Cd(Ⅱ) toxic metal ions, Chin. Chem. Lett. 25(2014) 601-604.

    18. [18]

      [18] H. Wang, X.Z. Yuan, Z.B. Wu, et al., Removal of basic dye from aqueous solution using Cinnamomum camphora sawdust:kinetics, isotherms, thermodynamics, and mass-transfer processes, Sep. Sci. Technol. 49(2014) 2689-2699.

    19. [19]

      [19] S.S. Li, X.Z. Kong, X.B. Jiang, X.L. Zhu, A novel and simple pathway to synthesis of porous polyurea absorbent and its tests on dye adsorption and desorption, Chin. Chem. Lett. 24(2013) 287-290.

  • 加载中
    1. [1]

      Zixuan ZhuXianjin ShiYongfang RaoYu Huang . Recent progress of MgO-based materials in CO2 adsorption and conversion: Modification methods, reaction condition, and CO2 hydrogenation. Chinese Chemical Letters, 2024, 35(5): 108954-. doi: 10.1016/j.cclet.2023.108954

    2. [2]

      Yue LiMinghao FanConghui WangYanxun LiXiang YuJun DingLei YanLele QiuYongcai ZhangLonglu Wang . 3D layer-by-layer amorphous MoSx assembled from [Mo3S13]2- clusters for efficient removal of tetracycline: Synergy of adsorption and photo-assisted PMS activation. Chinese Chemical Letters, 2024, 35(9): 109764-. doi: 10.1016/j.cclet.2024.109764

    3. [3]

      Linshan PengQihang PengTianxiang JinZhirong LiuYong Qian . Highly efficient capture of thorium ion by citric acid-modified chitosan gels from aqueous solution. Chinese Chemical Letters, 2024, 35(5): 108891-. doi: 10.1016/j.cclet.2023.108891

    4. [4]

      Xiao-Hong YiChong-Chen Wang . Metal-organic frameworks on 3D interconnected macroporous sponge foams for large-scale water decontamination: A mini review. Chinese Chemical Letters, 2024, 35(5): 109094-. doi: 10.1016/j.cclet.2023.109094

    5. [5]

      Haodong WangXiaoxu LaiChi ChenPei ShiHouzhao WanHao WangXingguang ChenDan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473

    6. [6]

      Dan LuoJinya TianJianqiao ZhouXiaodong Chi . Anthracene-bridged "Texas-sized" box for the simultaneous detection and uptake of tryptophan. Chinese Chemical Letters, 2024, 35(9): 109444-. doi: 10.1016/j.cclet.2023.109444

    7. [7]

      Yuqing WangZhemin LiQingjun LuQizhao LiJiaxin LuoChengjie LiYongshu Xie . Solar cells based on doubly concerted companion dyes with the efficiencies modulated by inserting an ethynyl group at different positions. Chinese Chemical Letters, 2024, 35(5): 109093-. doi: 10.1016/j.cclet.2023.109093

    8. [8]

      Supphachok ChanmungkalakulSyed Ali Abbas AbediFederico J. HernándezJianwei XuXiaogang Liu . The dark side of cyclooctatetraene (COT): Photophysics in the singlet states of “self-healing” dyes. Chinese Chemical Letters, 2024, 35(8): 109227-. doi: 10.1016/j.cclet.2023.109227

    9. [9]

      Yongkang YueZhou XuKaiqing MaFangjun HuoXuemei QinKuanshou ZhangCaixia Yin . HSA shrinkage optimizes the photostability of embedded dyes fundamentally to amplify their efficiency as photothermal materials. Chinese Chemical Letters, 2024, 35(8): 109223-. doi: 10.1016/j.cclet.2023.109223

    10. [10]

      Cunjun LiWencong LiuXianlei ChenLiang LiShenyu LanMingshan Zhu . Adsorption and activation of peroxymonosulfate on BiOCl for carbamazepine degradation: The role of piezoelectric effect. Chinese Chemical Letters, 2024, 35(10): 109652-. doi: 10.1016/j.cclet.2024.109652

    11. [11]

      Shuqi YuYu YangKeisuke KurodaJian PuRui GuoLi-An Hou . Selective removal of Cr(Ⅵ) using polyvinylpyrrolidone and polyacrylamide co-modified MoS2 composites by adsorption combined with reduction. Chinese Chemical Letters, 2024, 35(6): 109130-. doi: 10.1016/j.cclet.2023.109130

    12. [12]

      Shuanglin TIANTinghong GAOYutao LIUQian CHENQuan XIEQingquan XIAOYongchao LIANG . First-principles study of adsorption of Cl2 and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482

    13. [13]

      Xiao LiWanqiang YuYujie WangRuiying LiuQingquan YuRiming HuXuchuan JiangQingsheng GaoHong LiuJiayuan YuWeijia Zhou . Metal-encapsulated nitrogen-doped carbon nanotube arrays electrode for enhancing sulfion oxidation reaction and hydrogen evolution reaction by regulating of intermediate adsorption. Chinese Chemical Letters, 2024, 35(8): 109166-. doi: 10.1016/j.cclet.2023.109166

    14. [14]

      Xue ZhaoMengshan ChenDan WangHaoran ZhangGuangzhi HuYingtang Zhou . Ultrafine nano-copper derived from dopamine polymerization & synchronous adsorption achieve electrochemical purification of nitrate to ammonia in complex water environments. Chinese Chemical Letters, 2024, 35(8): 109327-. doi: 10.1016/j.cclet.2023.109327

    15. [15]

      Yu-Hang LiShuai GaoLu ZhangHanchun ChenChong-Chen WangHaodong Ji . Insights on selective Pb adsorption via O 2p orbit in UiO-66 containing rich-zirconium vacancies. Chinese Chemical Letters, 2024, 35(8): 109894-. doi: 10.1016/j.cclet.2024.109894

    16. [16]

      Yan WangHuixin ChenFuda YuShanyue WeiJinhui SongQianfeng HeYiming XieMiaoliang HuangCanzhong Lu . Oxygen self-doping pyrolyzed polyacrylic acid as sulfur host with physical/chemical adsorption dual function for lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(7): 109001-. doi: 10.1016/j.cclet.2023.109001

    17. [17]

      Linhui LiuWuwan XiongMingli FuJunliang WuZhenguo LiDaiqi YePeirong Chen . Efficient NOx abatement by passive adsorption over a Pd-SAPO-34 catalyst prepared by solid-state ion exchange. Chinese Chemical Letters, 2024, 35(4): 108870-. doi: 10.1016/j.cclet.2023.108870

    18. [18]

      Ruiying Liu Li Zhao Baishan Liu Jiayuan Yu Yujie Wang Wanqiang Yu Di Xin Chaoqiong Fang Xuchuan Jiang Riming Hu Hong Liu Weijia Zhou . Modulating pollutant adsorption and peroxymonosulfate activation sites on Co3O4@N,O doped-carbon shell for boosting catalytic degradation activity. Chinese Journal of Structural Chemistry, 2024, 43(8): 100332-100332. doi: 10.1016/j.cjsc.2023.100332

Metrics
  • PDF Downloads(0)
  • Abstract views(540)
  • HTML views(41)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return