Citation: Tian-Fang Cui, Jing Zhang, Xin-Dong Jiang, Ya-Jun Su, Chang-Liang Sun, Jiu-Li Zhao. Synthesis dibromo substituted BOPHY dye for the singlet oxygen generation[J]. Chinese Chemical Letters, ;2016, 27(02): 190-194. doi: 10.1016/j.cclet.2015.11.010 shu

Synthesis dibromo substituted BOPHY dye for the singlet oxygen generation

a.
a. College of Applied Chemistry, Key Laboratory of Rare-earth Chemistry and Applying Liaoning Province, Shenyang University of Chemical Technology, Shenyang 110142, China;
b.
b. Center of Physical and Chemistry Test, Shenyang University of Chemical Technology, Shenyang 110142, China

Corresponding author: Xin-Dong Jiang,
Received Date: 19 October 2015
Available Online: 13 November 2015
Fund Project: This work was supported by NNSFC (No. 21542004) (No. 21542004) the Program for Liaoning Excellent Talents in University (No. LJQ2015087) (No. LJQ2015087) the Public Research Foundation of Liaoning Province for the Cause of Science (No. 2014003009) (No. 2014003009) Educational Department of Liaoning Province (No. L2014170) (No. L2014170) the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry, and the start-up funds from Shenyang University of Chemical Technology. (No. 2013304007)

A dibromo substituted BOPHY derivative (2) was prepared and found to exhibit photo-sensitization capability. Rapid oxidation of 80% DPBF at the first 6 min was observed suggesting that 2 is a superior photo-sensitizer than methylene blue. The HOMO-LUMO band gap for the lowest energy absorption bands of the BOPHY 1 is smaller than that of PS 2, which is in good agreement with the red shift in the absorption observed between 1 and 2.
- BOPHY,
- Singlet oxygen,
- Photosensitizer,
- Photophysical property,
- DFT
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