Citation: Chun-Hua Ma, Jing Zhang, Yong-Cong Hong, Yi-Ru Wang, Xi Chen. Determination of carbendazim in tea using surface enhanced Raman spectroscopy[J]. Chinese Chemical Letters, ;2015, 26(12): 1455-1459. doi: 10.1016/j.cclet.2015.10.015 shu

Determination of carbendazim in tea using surface enhanced Raman spectroscopy

1.
a College of Tea and Food Science/Collaborative Innovation Center of Chinese Oolong Tea Industry, Wuyi University, Wuyishan 354300, China;
2.
b Department of Chemistry and The MOE Key Laboratory of Spectrochemical Analysis & Instrumentation, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Corresponding author: Xi Chen,
Received Date: 6 September 2015
Available Online: 22 October 2015

Surface-enhanced Raman scattering (SERS) is applied to detect the concentration of carbendzim (CBZ) in tea leaves. Au colloid is selected and used for active surfaces, and the extraction conditions are optimized in the experiment. The linearity range for the SERS intensity and the concentration of CBZ is found to be 0.5 to 8 mg kg^-1. The detection limit for CBZ is 0.1 mg kg^-1 and its recovery in tea samples is 72.3%. The detection results for CBZ using this method are compared with those of HPLC, and no obvious difference can be found. In addition, by dripping the condensed Au colloid on the tea leaves, the proposed SERS approach could be used to the in-situ determination of the half life period of CBZ on tea leaves.
- Carbendazim
1. [1]
  [1] Z.H. Wei, J. Xu, M.X. Guo, A.M. Shi, Research progress of carbendazim in China, J. Anhui Agric. Sci. 43 (2015) 125-127.
2. [2]
  [2] P.S. Daundkar, S. Rampal, Evaluation of ameliorative potential of selenium on carbendazim induced oxidative stress in male goats, Environ. Toxicol. Pharm. 38 (2014) 711-719.
3. [3]
  [3] F.R. Dollish, W.D. Fateley, F.F. Bentley, Characteristic Raman Frequencies of Organic Compounds, Chinese Chemical Society, Beijing, 1980.
4. [4]
  [4] General administration of quality supervision inspection and quarantine of the People's Republic of China,GB 2763-2014., National food safety standardmaximum residue limits for pesticides in food, Standard Press of China, Beijing, 2014, pp. 54.
5. [5]
  [5] J. Wang, W. Cheung, D. Leung, Determination of pesticide residue transfer rates (percent) fromdried tea leaves to brewedtea, J.Agric. Food Chem. 62 (2014) 966-983.
6. [6]
  [6] Q.H. Wu, Y.P. Li, C. Wang, et al., Dispersive liquid-liquid microextraction combined with high performance liquid chromatography-fluorescence detection for the determination of carbendazim and thiabendazole in environmental samples, Anal. Chim. Acta 638 (2009) 139-145.
7. [7]
  [7] Z.M. Liu, W.H. Liu, Q.H. Wu, et al., Determination of carbendazim and thiabendazole in apple juice by hollow fibre-based liquid phase microextraction-high performance liquid chromatography with fluorescence detection, Int. J. Environ. Anal. Chem. 92 (2012) 582-591.
8. [8]
  [8] C.A. Razzino, L.F. Sgobbi, T.C. Canevari, J. Cancino, S.A.S. Machado, Sensitive determination of carbendazim in orange juice by electrode modified with hybrid material, Food Chem. 170 (2015) 360-365.
9. [9]
  [9] Y.J. Guo, S.J. Guo, J. Li, E.K. Wang, S.J. Dong, Cyclodextrin-graphene hybrid nanosheets as enhanced sensing platform for ultrasensitive determination of carbendazim, Talanta 84 (2011) 60-64.
10. [10]
  [10] L. Rubio, M.C. Ortiz, L.A. Sarabia, Identification and quantification of carbamate pesticides in dried lime tree flowers by means of excitation-emission molecular fluorescence and parallel factor analysis when quenching effect exists, Anal. Chim. Acta 820 (2014) 9-22.
11. [11]
  [11] Y.Q. Zhu, L. Zhang, L.B. Yang, Designing of the functional paper-based surfaceenhanced Raman spectroscopy substrates for colorants detection, Mater. Res. Bull. 63 (2015) 199-204.
12. [12]
  [12] Y.Y. Zhang, W.S. Yu, L. Pei, et al., Rapid analysis of malachite green and leucomalachite green in fish muscles with surface-enhanced resonance Raman scattering, Food Chem. 169 (2015) 80-84.
13. [13]
  [13] A.Y. Panarin, I.A. Khodasevich, O.L. Gladkova, S.N. Terekhov, Determination of antimony by surface-enhanced Raman spectroscopy, Appl. Spectrosc. 68 (2014) 297-306.
14. [14]
  [14] Y.D. Liu, B.B. He, Y.X. Zhang, H.Y. Wang, B. Ye, Detection of phosmet residues on navel orange skin by surface-enhanced Raman spectroscopy, Intell. Autom. Soft Comput. 21 (2015) 423-432.
15. [15]
  [15] Q.Q. Li, Y.P. Du, Y. Xu, et al., Rapid and sensitive detection of pesticides by surfaceenhanced Raman spectroscopy technique based on glycidyl methacrylate-ethylene dimethacrylate (GMA-EDMA) porous material, Chin. Chem. Lett. 24 (2013) 332-334.
16. [16]
  [16] Z. Zhang, Q.S. Yu, H. Li, A. Mustapha, M.S. Lin, Standing gold nanorod arrays as reproducible SERS substrates for measurement of pesticides in apple juice and vegetables, J. Food Sci. 80 (2015) N450-N458.
17. [17]
  [17] X.H. Tang, R.L. Dong, L.B. Yang, J.H. Liu, Fabrication of Au nanorod-coated Fe₃O₄ microspheres as SERS substrate for pesticide analysis by near-infrared excitation, J. Raman Spectrosc. 46 (2015) 470-475.
18. [18]
  [18] T.X. Yang, X.Y. Guo, H. Wang, et al., Au dotted magnetic network nanostructure and its application for on-site monitoring femtomolar level pesticide, Small 7 (2014) 1325-1331.
19. [19]
  [19] A.D. Strickland, C.A. Batt, Detection of carbendazim by surface-enhanced Raman scattering using cyclodextrin inclusion complexes on gold nanorods, Anal. Chem. 81 (2009) 2895-2903.
20. [20]
  [20] X. Wang, Y.P. Du, H. Zhang, et al., Fast enrichment and ultrasensitive in-situ detection of pesticide residues on oranges with surface-enhanced Raman spectroscopy based on Au nanoparticles decorated glycidyl methacrylate-ethylene dimethacrylate material, Food Control 46 (2014) 108-114.
21. [21]
  [21] G. Frens, Controlled nucleation for the regulation of the particle size in monodisperse gold suspensions, Nat. Phys. Sci. 241 (1973) 20-22.
22. [22]
  [22] X.B. Wang, R.M. Wu, M.H. Liu, et al., Laser Raman spectrum analysis of carbendazim pesticide, Spectrosc. Spect. Anal. 34 (2014) 1566-1570.
23. [23]
  [23] A. Ü nal, B. Eren, FT-IR, dispersive Raman, NMR, DFT and antimicrobial activity studies on 2-(thiophen-2-yl)-1H-benzo[d]imidazole, Spectrochim. Acta, A: Mol. Biomol. Spectrosc. 114 (2013) 129-136.
24. [24]
  [24] D. Fan, X.Z. Gan, Y.Y. Lu, et al., Dissipation dynamics of carbendazim in tea, J. Agro- Environ. Sci. 24 (2005) 298-300.
25. [25]
  [25] P.A. Devi, M. Paramasivam, V. Prakasam, Degradation pattern and risk assessment of carbendazim and mancozeb in mango fruits, Environ. Monit. Assess. 187 (2015) 4142.

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