Citation: Fei-Fei Li, Jun-Nan Gu, Xiao-Chun Zhou. Single molecule electro-catalysis of non-fluorescent molecule[J]. Chinese Chemical Letters, ;2015, 26(12): 1514-1517. doi: 10.1016/j.cclet.2015.09.013 shu

Single molecule electro-catalysis of non-fluorescent molecule

1.
Division of Advanced Nanomaterials, Suzhou Institute of Nano-tech and Nano-bionics, Chinese Academy of Sciences, Suzhou 215125, China

Corresponding author: Xiao-Chun Zhou,
Received Date: 17 August 2015
Available Online: 1 September 2015

Single molecule catalysis is very powerful in revealing catalytic mechanism at the single molecule level. But fluorescentmolecule is always necessary to take part into the catalysis directly in previous research. In order to study the single molecule electro-catalysis of non-fluorescentmolecule (SMECNFM) on nanocatalyst, we couple the SMECNFM with a single molecule fluorescence reaction. A certain number of fluorescent molecules will be generated and detected when the SMECNFM happens. Through this method, we can detect the electro-oxidation reaction of one HCOONamolecule. The stability of Pt nanocatalyst supported on active carbon is studied at the singlemolecule level by this method. This paper also provides a general way to make ultra-sensitive sensor, and to study the SMECNFM for the molecules, such as formic acid, hydrogen, oxygen, etc., on single nanoparticle.
- Single molecule catalysis
1. [1]
  [1] X. Zhao, M. Yin, L. Ma, et al., Recent advances in catalysts for direct methanol fuel cells, Energy Environ. Sci. 4 (2011) 2736-2753.
2. [2]
  [2] Z.H. Zhou, S.L. Wang, W.J. Zhou, et al., Novel synthesis of highly active Pt/C cathode electrocatalyst for direct methanol fuel cell, Chem. Commun. (2003) 394-395.
3. [3]
  [3] Y. Zhu, Y. Kang, Z. Zou, et al., A facile preparation of carbon-supported Pd nanoparticles for electrocatalytic oxidation of formic acid, Electrochem. Commun. 10 (2008) 802-805.
4. [4]
  [4] B. O'Regan, M. Gratzel, A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO₂ films, Nature 353 (1991) 737-740.
5. [5]
  [5] D. Chen, J. Li, Interfacial design and functionization on metal electrodes through self-assembled monolayers, Surf. Sci. Rep. 61 (2006) 445-463.
6. [6]
  [6] J.B. Sperry, D.L.Wright, The application of cathodic reductions andanodic oxidations in the synthesis of complex molecules, Chem. Soc. Rev. 35 (2006) 605-621.
7. [7]
  [7] H.P. Lu, L.Y. Xun, X.S. Xie, Single-molecule enzymatic dynamics, Science 282 (1998) 1877-1882.
8. [8]
  [8] W. Xu, J.S. Kong, Y.T.E. Yeh, P. Chen, Single-molecule nanocatalysis reveals heterogeneous reaction pathways and catalytic dynamics, Nat. Mater. 7 (2008) 992-996.
9. [9]
  [9] X. Zhou, N.M. Andoy, G. Liu, et al., Quantitative super-resolution imaging uncovers reactivity patterns on single nanocatalysts, Nat. Nano 7 (2012) 237-241.
10. [10]
  [10] T. Tachikawa, T. Majima, Single-molecule fluorescence imaging of TiO₂ photocatalytic reactions, Langmuir 25 (2009) 7791-7802.
11. [11]
  [11] M.B.J. Roeffaers, B.F. Sels, H. Uji-i, et al., Spatially resolved observation of crystal-face-dependent catalysis by single turnover counting, Nature 439 (2006) 572-575.
12. [12]
  [12] W. Wang, J. Gu, T. He, et al., Optical super-resolution microscopy and its applications in nano-catalysis, Nano Res. 8 (2015) 441-455.
13. [13]
  [13] W. Xu, H. Shen, Y.J. Kim, et al., Single-molecule electrocatalysis by single-walled carbon nanotubes, Nano Lett. 9 (2009) 3968-3973.
14. [14]
  [14] X. Xiao, F.R.F. Fan, J. Zhou, A.J. Bard, Current transients in single nanoparticle collision events, J. Am. Chem. Soc. 130 (2008) 16669-16677.
15. [15]
  [15] S.J. Kwon, F.R.F. Fan, A.J. Bard, Observing iridium oxide (IrOx) single nanoparticle collisions at ultramicroelectrodes, J. Am. Chem. Soc. 132 (2010) 13165- 13167.
16. [16]
  [16] X. Xiao, A.J. Bard, Observing single nanoparticle collisions at an ultramicroelectrode by electrocatalytic amplification, J. Am. Chem. Soc. 129 (2007) 9610-9612.
17. [17]
  [17] H. Zhou, J.H. Park, F.R.F. Fan, A.J. Bard, Observation of single metal nanoparticle collisions by open circuit (mixed) potential changes at an ultramicroelectrode, J. Am. Chem. Soc. 134 (2012) 13212-13215.
18. [18]
  [18] X. Zhou, P. Chen, Application of optical super resolution imaging technology in single nanoparticle catalysis, in: 9th Sino-US Symposium on Nanoscale Science and Technology, Tianjin, 2014.
19. [19]
  [19] K.S. Han, G. Liu, X. Zhou, R.E. Medina, P. Chen, How does a single pt nanocatalyst behave in two different reactions? A single-molecule study, Nano Lett. 12 (2012) 1253-1259.
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沈阳化工大学材料科学与工程学院沈阳 110142