Citation: Zhi-Lin Cheng, Wei Sun. Preparation of nano-CuO-loaded halloysite nanotubes with high catalytic activity for selective oxidation of cyclohexene[J]. Chinese Chemical Letters, ;2016, 27(01): 81-84. doi: 10.1016/j.cclet.2015.08.002 shu

Preparation of nano-CuO-loaded halloysite nanotubes with high catalytic activity for selective oxidation of cyclohexene

Zhi-Lin Cheng ^, ,
Wei Sun

1.
College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, China

Corresponding author: Zhi-Lin Cheng,
Received Date: 10 June 2015
Available Online: 10 June 2015
Fund Project: This work was supported by the Talent Introduction Fund of Yangzhou University, Jiangsu Social Development Project(No. BE2014613) (No. BE2014613)Six Talent Peaks of Jiangsu Province(No. 2014-XCL-013). (No. 2014-XCL-013)

A facile preparation method of nano-CuO catalysts, assembled in the hollow nanotube of halloysite nanotubes(HNTs), was developed. The characterizations of XRD, TEM, SEM, BET, XRF and FT-IR were used to analyze the structure and properties of the nano-CuO/HNT loaded catalyst. The XRD patterns indicated that the CuO nanoparticles on HNTs were monoclinic phase. The TEM-EDX and SEM images confirmed that most of nano-CuO catalysts with the crystal size of ca. 20 nm were assembled into the hollow nanotube of HNTs. The catalytic performance of the nano-CuO/HNT catalysts was evaluated by using selective oxidation of cyclohexene. The reaction temperature and recycling times were investigated. The results reveal that the nano-CuO/HNT catalysts exhibit an excellent catalytic oxidation performance for selective oxidation of cyclohexene to 2-cyclohexene-1-one.
- Cyclohexene,
- CuO,
- Selective oxidation,
- HNTs
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