Citation: Jun-Ke Wang, Ying-Xiao Zong, Xi-Cun Wang, Yu-Lai Hu, Guo-Ren Yue. Synthesis of N-benzothiazol-2-yl-amides by Pd-catalyzed C(sp²)-H functionalization[J]. Chinese Chemical Letters, ;2015, 26(11): 1376-1380. doi: 10.1016/j.cclet.2015.08.001 shu

Synthesis of N-benzothiazol-2-yl-amides by Pd-catalyzed C(sp²)-H functionalization

Jun-Ke Wang ^a,b,c ,
Ying-Xiao Zong ^a,b ,
Xi-Cun Wang ^a,b,, ,
Yu-Lai Hu ^a,b,, ,
Guo-Ren Yue ^a

1.
a Key Laboratory of Hexi Corridor Resources Utilization of Gansu Universities, College of Chemistry and Chemical Engineering, Hexi University, Zhangye 734000, China;
2.
b Gansu Key Laboratory of Polymer Materials, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, China;
3.
c Gansu Engineering Laboratory of Applied Mycology, Hexi University, Zhangye 734000, China

Corresponding author: Xi-Cun Wang, Yu-Lai Hu,
Received Date: 11 May 2015
Available Online: 1 July 2015

A catalytic synthesis of N-benzothiazol-2-yl-amides from 1-acyl-3-(phenyl)thioureas was achieved in the presence of a palladium catalyst through the C(sp²)-H functionalization/C-S bond formation. This synthetic methodology can produce various N-benzothiazol-2-yl-amides in high yields with good functional group tolerance.
- Benzothiazole
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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of N-benzothiazol-2-yl-amides by Pd-catalyzed C(sp2)-H functionalization

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通讯作者: 陈斌, bchen63@163.com

Synthesis of N-benzothiazol-2-yl-amides by Pd-catalyzed C(sp²)-H functionalization