Citation: Hui Xia, Hai-Long Wu, Hui-Wen Gu, Xiao-Li Yin, Huan Fang, Ru-Qin Yu. Simultaneous determination of naphazoline and pyridoxine in eye drops using excitation-emission matrix fluorescence coupled with second-order calibration method based on alternating trilinear decomposition algorithm[J]. Chinese Chemical Letters, ;2015, 26(12): 1446-1449. doi: 10.1016/j.cclet.2015.07.015 shu

Simultaneous determination of naphazoline and pyridoxine in eye drops using excitation-emission matrix fluorescence coupled with second-order calibration method based on alternating trilinear decomposition algorithm

1.
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China

Corresponding author: Hai-Long Wu,
Received Date: 18 March 2015
Available Online: 19 June 2015

A novel method is developed for the direct determination of naphazoline hydrochloride (NAP) and pyridoxine hydrochloride (VB6) in commercial eye drops. By using excitation-emission matrix (EEM) fluorescence coupled with second-order calibration method based on the alternating trilinear decomposition (ATLD) algorithm, the proposed approach can achieve quantitative analysis successfully even in the presence of unknown and uncalibrated interferences. The method shows good linearity for NAP and VB6 with correlation coefficients greater than 0.99. The results were in good agreement with the labeled contents. To further confirm the feasibility and reliability of the proposed method, the same batch samples were analyzed by multiple reaction monitoring (MRM) based on LC-MS/MS method. T-test demonstrated that there are no significant differences between the prediction results of the two methods. The satisfactory results obtained in this work indicate that the use of the second-order calibration method coupled with the EEM is a promising tool for industrial quality control and pharmaceutical analysis due to its advantages of high sensitivity, low-cost and simple implementation.
- Excitation-emission matrix fluorescence
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沈阳化工大学材料科学与工程学院沈阳 110142