Citation: Hao-Ran Xu, Kun Li, Shu-Yan Jiao, Ling-Ling Li, Sheng-Lin Pan, Xiao-Qi Yu. Tetraphenylethene based zinc complexes as fluorescent chemosensors for pyrophosphate sensing[J]. Chinese Chemical Letters, ;2015, 26(7): 877-880. doi: 10.1016/j.cclet.2015.05.037 shu

Tetraphenylethene based zinc complexes as fluorescent chemosensors for pyrophosphate sensing

1.
Key Laboratory of Green Chemistry and Technology, Ministry of Education, College of Chemistry, Sichuan University, Chengdu 610064, China

Corresponding author: Kun Li, Xiao-Qi Yu,
Received Date: 25 January 2015
Available Online: 24 April 2015
Fund Project: This work was financially supported by the National Program on Key Basic Research Project of China (973 Program, Nos. 2012CB720603, 2013CB328900) (973 Program, Nos. 2012CB720603, 2013CB328900)

We described a serious of zinc complexes that exhibit characteristic fluorescence responses toward pyrophosphate (PPi) and adenosine triphosphate (ATP) in aqueous media. These novel probes exploited tetraphenylethene (TPE) as fluorophore and macrocycle-polyamine (including 1,4,7,10-tetraazacyclododecane and 1,4,7-triazacyclononane) Zn(II) complexes as binding group. These “OFF-ON” type probes exhibited promising selectivity and sensitivity to PPi and ATP via a restriction of intramolecular rotation (RIR) mechanism. The detection limit for PPi was found within nmol/L range.
- Tetraphenylethene,
- Cyclen,
- Pyrophosphates,
- Zinc complex
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沈阳化工大学材料科学与工程学院沈阳 110142