Citation: Teng-Jie Ren, Juan Zhang, Yan-Hui Hu, Jun-Pan Li, Meng-Shuai Liu, Di-Shun Zhao. Extractive desulfurization of fuel oil with metal-based ionic liquids[J]. Chinese Chemical Letters, ;2015, 26(9): 1169-1173. doi: 10.1016/j.cclet.2015.05.023 shu

Extractive desulfurization of fuel oil with metal-based ionic liquids

1.
1 College of Chemistry and Pharmaceutical Engineering, Hebei University of Science and Technology, Shijiazhuang 050018, China;
2.
2 The Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin 150080, China

Corresponding author: Juan Zhang,
Received Date: 5 February 2015
Available Online: 29 April 2015
Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 21106032) (No. 21106032)

Several metal-based ionic liquids (ILs) were synthesized and used as extractants for the desulfurization of dibenzothiophene (DBT) in simulated fuel oil. The effects of several anion and metal ions, n(ILs)/n(metal) as mole ratio, V_IL/V_oil and extractive times on the removal ratio of DBT were investigated in detail. The results showed that [BMIM]HSO₄/FeCl₃(BMIM was short for 1-butyl-3-methyl imidazole) was superior to the other ILs for the extractive desulfurization. A total of 100% of DBT was removed at room temperature in 5 min with V_[BMIM]HSO₄=FeCl₃=V_oil=1:1. The extractive activity of [BMIM]HSO₄/FeCl₃ IL did not change almost after five runs. Extractive desulfurization of different sulfur compounds and commercial diesel fuel oil were also examined. The removal ratios of the sulfur compounds as the reaction substrates were all over 90% and the sulfur content of commercial diesel oil decreased to 120 ppm from 12,400 ppm.
- Ionic liquids,
- Extractive desulfurization,
- [BMIM]HSO₄/FeCl₃,
- Dibenzothiophene
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