Citation: Juan-Juan Sun, Ying Han, Jing Sun, Chao-Guo Yan. Synthesis and crystal structure of Ni, Cu complexes of 5-methyl-10,10,15,15,20,20-hexaethylcalix[4]pyrrole mono-Schiff bases[J]. Chinese Chemical Letters, ;2015, 26(6): 685-689. doi: 10.1016/j.cclet.2015.03.028 shu

Synthesis and crystal structure of Ni, Cu complexes of 5-methyl-10,10,15,15,20,20-hexaethylcalix[4]pyrrole mono-Schiff bases

1.
College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002, China

Corresponding author: Ying Han, Chao-Guo Yan,
Received Date: 20 November 2014
Available Online: 17 March 2015
Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 21172190) (No. 21172190)

The functionalized calix[4]pyrrole meso-substituted Schiff bases were conveniently prepared by fourstep synthetic route. Furthermore, the nickel and copper complexes of calix[4]pyrrolemeso-substituted Schiff base with 1:2 stoichiometry were obtained. The crystal structures of the calix[4]pyrroles and their metal complexes were determined by X-ray diffraction.
- Calix[4]pyrrole,
- Schiff base,
- Macrocycle,
- Metal complex,
- Crystal structure
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