Citation: Feng-Hua Zhao, Ruo-Jin Liu, Xiao-Yan Yu, Cheng-Chun Tang, Xiong-Wei Qua, Qing-Xin Zhang. Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer[J]. Chinese Chemical Letters, ;2015, 26(6): 727-729. doi: 10.1016/j.cclet.2015.03.025 shu

Synthesis of a novel naphthyl-based self-catalyzed phthalonitrile polymer

Feng-Hua Zhao ^a ,
Ruo-Jin Liu ^a ,
Xiao-Yan Yu ^a,b,, ,
^c ,
Cheng-Chun Tang ^b ,
Xiong-Wei Qua ^b ,
Qing-Xin Zhang ^a,b,,

1.
a Institute of Polymer Science and Engineering, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin 300130, China;
2.
b Key Lab for Micro-and Nano-Scale Boron Nitride Materials in Hebei Province, Hebei University of Technology, Tianjin 300130, China;
3.
c National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba-city, Ibaraki 305-0047, Japan

Corresponding author: Xiao-Yan Yu, Qing-Xin Zhang,
Received Date: 1 December 2014
Available Online: 12 March 2015
Fund Project:

A novel naphthyl-based self-catalyzed phthalonitrile monomer was prepared via nucleophilic displacement reaction. The structure was characterized by Fourier infrared spectrum (FT-IR) and nuclear magnetic resonance (¹H NMR). The polymerization mechanism was explored. Thermal properties were characterized by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA), which demonstrated self-promoted behavior and excellent heat resistance.
- Phthalonitrile polymer,
- Self-catalyzed,
- Thermal properties,
- Heat resistance
1. [1]
  [1] M. Laskoski, A. Neal, T.M. Keller, et al., Improved synthesis of oligomeric phthalonitriles and studies designed for low temperature cure, J. Polym. Sci. A: Polym. Chem. 52 (2014) 1662-1668.
2. [2]
  [2] K. Zeng, K. Zhou, S. Zhou, et al., Studies on self-promoted cure behaviors of hydroxy-containing phthalonitrile model compounds, Eur. Polym. J. 45 (2009) 1328-1335.
3. [3]
  [3] B. Amir, R.K. Michael, H. Zhou, et al., An efficient approach to prepare ether and amide-based self-catalyzed phthalonitrile resins, Polym. Chem. 4 (2013) 3617-3622.
4. [4]
  [4] Z.B. Zhang, Z. Li, H. Zhou, et al., Self-catalyzed silicon-containing phthalonitrile resins with low melting point, excellent solubility and thermal stability, J. Appl. Polym. Sci. 131 (2014) 40919.
5. [5]
  [5] S.H. Zhou, H.B. Hong, K. Zeng, et al., Synthesis, characterization and self-promoted cure behaviors of a new phthalonitrile derivative 4-(4-(3,5-diaminobenzoyl)phenoxy) phthalonitrile, Polym. Bull. 62 (2009) 581-591.
6. [6]
  [6] H. Guo, Z.R. Chen, J.D. Zhang, et al., Self-promoted curing phthalonitrile with high glass transition temperature for advanced composites, J. Polym. Res. 19 (2012) 9918.
7. [7]
  [7] B. Amir, H. Zhou, F. Liu, H. Aurangzeb, Synthesis and characterization of selfcatalyzed imide-containing pthalonitrile resins, J. Polym. Sci. A: Polym. Chem. 48 (2010) 5916-5920.
8. [8]
  [8] K. Zeng, K. Zhou, W.R. Tang, et al., Synthesis and curing of a novel aminocontaining phthalonitrile derivative, Chin. Chem. Lett. 18 (2007) 523-526.
9. [9]
  [9] A.W. Snow, J.R. Griffith, N.P. Marullo, Syntheses and characterization of heteroatom-bridged metal-free phthalocyanine network polymers and model compounds, Macromolecules 17 (1984) 1614-1624.
10. [10]
  [10] T.M. Keller, D.D. Dominguez, High temperature resorcinol-based phthalonitrile polymer, Polymer 46 (2005) 4614-4618.
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