Citation: Hai-Hua Li. Tf₂NH-catalyzed, highly regio-and stereo-selective synthesis of trisubstituted alkenes and indane derivatives from benzylic alcohols and alkenes[J]. Chinese Chemical Letters, ;2015, 26(3): 320-322. doi: 10.1016/j.cclet.2015.01.028 shu

Tf₂NH-catalyzed, highly regio-and stereo-selective synthesis of trisubstituted alkenes and indane derivatives from benzylic alcohols and alkenes

Hai-Hua Li ^,

1.
Department of Environmental and Chemical Engineering, Tangshan College, Tangshan 063000, China

Corresponding author: Hai-Hua Li,
Received Date: 27 October 2014
Available Online: 20 January 2015

A reaction of benzylic alcohols with alkenes has been developed in the presence of bis(trifluoromethane) sulfonimide for the synthesis of trisubstituted alkenes and indane derivatives with high stereoselectivity. In general, benzylic alcohols react with 1,1-diaryl alkenes to afford trisubstituted alkenes, and the reaction with 1,2-disubstituted and trisubstituted alkenes affords indane derivatives through a [3 + 2] annulation reaction.
- Benzylic alcohol,
- Alkene,
- Indane derivative,
- [3 + 2] Annulation reaction
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沈阳化工大学材料科学与工程学院沈阳 110142

Tf2NH-catalyzed, highly regio-and stereo-selective synthesis of trisubstituted alkenes and indane derivatives from benzylic alcohols and alkenes

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通讯作者: 陈斌, bchen63@163.com

Tf₂NH-catalyzed, highly regio-and stereo-selective synthesis of trisubstituted alkenes and indane derivatives from benzylic alcohols and alkenes