Citation: Hua-Hua Wang, Yi-Yu Jiang, Mian HR Mahmood, Hai-Yang Liu, Herman H.Y. Sung, Ian D. Williams, Chi K. Chang. β-Octafl uorinated tetrakis(ethoxycarbonyl)porphyrin[J]. Chinese Chemical Letters, ;2015, 26(5): 529-533. doi: 10.1016/j.cclet.2015.01.026 shu

β-Octafl uorinated tetrakis(ethoxycarbonyl)porphyrin

1.
a Department of Chemistry, South China University of Technology, Guangzhou 510641, China;
2.
b Department of Chemistry, Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China;
3.
c Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA

Corresponding author: Hai-Yang Liu, Chi K. Chang,
Received Date: 26 November 2014
Available Online: 19 January 2015
Fund Project: This work was supported by National Natural Science Foundation of China (NNSFC) under Grant (Nos. 21171057, 21371059) (NNSFC)

Tetrakis(alkoxycarbonyl)porphyrin and its β-octafluoro-substituted derivatives were synthesized via Lindsey method and transformed to their zinc complexes. Single crystal X-ray structures of corresponding Zn(II) porphyrins revealed that β-octafluorination will give more compactness of porphyrin moieties in the crystal structure owing to the hydrogen bonding interactions involving bfluorine atoms. An unusual six-coordinated Zn(II) was found via intramolecular coordination of oxygen atom of meso-substituents with central Zn(II).
- Tetraalkyl porphyrin,
- Zinc,
- Ethyl glyoxylate,
- 3,4-Difluoropyrrole
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