Citation: Joseph Jankolovits, Jeff W. Kampf, Vincent L. Pecoraro. Assembly of zinc metallacrowns with an α-amino hydroxamic acid ligand[J]. Chinese Chemical Letters, ;2015, 26(4): 444-448. doi: 10.1016/j.cclet.2015.01.017 shu

Assembly of zinc metallacrowns with an α-amino hydroxamic acid ligand

1.
Chemistry Department, University of Michigan, Ann Arbor, MI 48109-1055, USA

Corresponding author: Vincent L. Pecoraro,
Received Date: 15 December 2014
Available Online: 25 December 2014
Fund Project:

In the assembly of metallacrowns for molecular recognition, luminescence, and molecular magnetism applications, substituting the ring ion can have profound effects on the structure, stability, and physical properties of the inorganic macrocycle. The assembly of Zn(Ⅱ) metallacrowns with an α-amino hydroxamic acid ligand (pheHA) was investigated to compare the assembly behavior with the well studied metallacrowns containing Cu(Ⅱ) and Ni(Ⅱ). Electrospray ionization mass spectrometry reveals that the benchmark species Zn₅(pheHA)₄²⁺ and LnZn₅(pheHA)₅³⁺ assemble in pyridine, which is consistent with the behavior of Cu(Ⅱ) and Ni(Ⅱ). A LnZn₄(pheHA)₄³⁺ species is also observed in a 1:1 DMF-pyridine mixture. An unprecedented La(Ⅲ)[16-MC_{Zn(Ⅱ),pheHA,HpheHA}-6]⁵⁺ complex was crystallographically characterized that possesses unusual C₂ symmetry. These results provide insights into the design of functional metallacrowns through ring ion substitution.
- Metallacrown,
- Self-assembly,
- Supramolecular chemistry,
- Lanthanides,
- Zinc
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