Citation: Hao Wang, Yi-Ping Chen, Zhu-Chai You, Meng-Xi Zhou, Ning Zhang, Yan-Qiong Sun. Synthesis and characterization of a new catalyst for RhB degradation constructed by [SiMo₁₂O₄₀]^4- anionic cluster[J]. Chinese Chemical Letters, ;2015, 26(2): 187-192. doi: 10.1016/j.cclet.2014.11.023 shu

Synthesis and characterization of a new catalyst for RhB degradation constructed by [SiMo₁₂O₄₀]^4- anionic cluster

1.
a College of Chemistry, Fuzhou University, Fuzhou 350108, China;
2.
b State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Yi-Ping Chen,
Received Date: 21 July 2014
Available Online: 29 September 2014
Fund Project: This research was financially supported by the National Science Foundation of China (Nos. 21473030, J1103303) (Nos. 21473030, J1103303) Fujian Provincial Natural Science Foundation (No. 2013J01042) (No. 2013J01042) Open Fund of State Key Laboratory of Structural Chemistry (No. 20130015) (No. 20130015)

A Keggin-type polyoxomolybdate [H₂biim]{Ni(biim)₃(SiMo₁₂O₄₀)} [biim=1H,1'H-[2,2']biimidazolyl] has been synthesized under hydrothermal condition and characterized by XRD, temperature-dependent IR, TG, temperature-induced and magnetism-induced 2D infrared correlation spectroscopy (2D-IR COS) and UV-vis DRS in order to explore the relationship between structure and properties. Temperatureinduced 2D-IR COS spectroscopy indicates that the terminal Mo-O_u/v bonds are more sensitive than the bridging Mo=O_t bands to temperature variation, which is in agreement with the conclusion of temperature-dependent IR. Magnetism-dependent 2D-IR COS spectroscopy reveals the stretching vibration of the Mo=O_t occurs prior to the stretching vibration of the Mo-O_u/v, which is due to the coordination environment and the valence of the Siatom. The stability of compound 1 is investigated via TG and temperature-dependent IR. In RhB degradation, compound 1 shows good photocatalytic abilities.
- 2D infrared correlation spectroscopy,
- Photocatalytic degradation of RhB,
- Silicon molybdenum polyoxometalate
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and characterization of a new catalyst for RhB degradation constructed by [SiMo12O40]4- anionic cluster

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通讯作者: 陈斌, bchen63@163.com

Synthesis and characterization of a new catalyst for RhB degradation constructed by [SiMo₁₂O₄₀]^4- anionic cluster