Citation: Hui-Ting Wang, Li-Hui Kong, Ping-Ping Shi, Qiang Li, Qiong Ye, Da-Wei Fu. The structure and dielectric properties of ionic compounds with flexible ammonium moiety[J]. Chinese Chemical Letters, ;2015, 26(3): 382-386. doi: 10.1016/j.cclet.2014.10.025 shu

The structure and dielectric properties of ionic compounds with flexible ammonium moiety

1.
Ordered Matter Science Research Center, Southeast University, Nanjing 211189, China

Corresponding author: Qiong Ye, Da-Wei Fu,
Received Date: 1 August 2014
Available Online: 15 October 2014
Fund Project: This work was financially supported by the Project 973 (No. 2014CB848800) (No. 2014CB848800)

The 3-morpholin-4-yl-propyl-ammine tetrafluoroborate (MPA⁺) (BF₄^-) (1) and the 3-morpholin-4-ylpropyl-ammine perchlorate (MPA⁺) (ClO₄^-) (2) were synthesized and separated as colorless block crystal. The (MPA⁺) (BF₄^-) undergoes a reversible phase transition at ca. 347.3 K with a hysteresis of 16.1 K. Dielectric measurement also can confirm the transition. The crystal structure determined at 300 K (monoclinic, P2₁/c, a = 9.978(2)Å, b= 7.5206(15)Å, c= 15.058(3)Å, β= 96.99(3)°, v= 1121.6(4)Å³, z= 4) and 373 K (triclinic, P-1, a = 10.021(7) Å,b = 7.662(3) Å, c= 7.920(4) Å, α= 95.012(14)°, β= 101.67(4)°, γ= 91.48(3)°, v= 592.7(6) Å³, z= 2) reveal that this compound has two phase. The most distinct is the BF₄^- anion is disorder at 373 K, which is probably the driving force of the phase transition. DSC measurement, dielectric measurement and the crystal structure of the compound 2 did not change at 300 K and 100 K.
- Phase transition,
- Dielectric,
- DSC
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