Citation: De-Bo Xiang, Hui-Bo Shao. Investigation of multilevel ion-pairing effect of triferrocenylmethane in organic phase[J]. Chinese Chemical Letters, ;2014, 25(10): 1379-1381. doi: 10.1016/j.cclet.2014.07.004 shu

Investigation of multilevel ion-pairing effect of triferrocenylmethane in organic phase

De-Bo Xiang ^a,b ,
Hui-Bo Shao ^a,,

1.
a Key Laboratory of Cluster Science (Ministry of Education of China), School of Chemistry, Beijing Institute of Technology, Beijing 100081, China;
b China Aviation Lithium Battery Co.
b China Aviation Lithium Battery Co., Ltd., Henan 471003, China

Corresponding author: Hui-Bo Shao,
Received Date: 22 May 2014
Available Online: 1 July 2014
Fund Project: The authors gratefully acknowledge the NSFC (No. 21173023) (No. 21173023) the 111 Project (No. B07012) in China and the TriFcM provided from professor Hua-Zhong Yu at Simon Fraser University in Canada. (No. B07012)

The intramolecular electronic communication and multilevel ion-pairing effect of triferrocenylmethane (TriFcM) in organic phase was studied with the ‘‘thin-layer electrochemistry'' approach. Three pairs of symmetric peaks in cyclic voltammetry of TriFcM correspond to three one-electron electrochemical reaction processes and indicate strong intramolecular electronic communication, which could be used to study the multilevel ion-pairing effect. Three different formation constants of ion-pairs between the three ferroceniums of TriFcM and perchlorate in thin organic film were obtained and compared.
- Triferrocenylmethane,
- Thin-layer electrochemistry,
- Intramolecular electronic communication,
- Multilevel ion-pairing effect
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