Citation: Li-Ping Wang, Guang Li, Wen-Zhi Li, Chao-Lei Ban, Yu-Chao Li, Cong Guo, Meng-Meng Zhang, Ling-Yun Liu, Na-Na Lu, Meng-Zhu Zheng. Copolymers with fluorescence properties in mesoporous silica SBA-15: Synthesis and characterization[J]. Chinese Chemical Letters, ;2014, 25(12): 1620-1624. doi: 10.1016/j.cclet.2014.06.028 shu

Copolymers with fluorescence properties in mesoporous silica SBA-15: Synthesis and characterization

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College of Materials Science and Engineering, Liaocheng University, Liaocheng 252059, China

Corresponding author: Li-Ping Wang,
Received Date: 11 April 2014
Available Online: 20 June 2014
Fund Project: This research was supported by the National Natural Science Foundation of China (No. 21203085) (No. 21203085)

A novel copolymer with fluorescence properties in mesoporous silica SBA-15 was prepared via a combination of surface-initiated reversible addition-fragmentation chain transfer (RAFT) polymerization and “click” chemistry. A sufficient amount of peroxide groups were introduced into mesoporous silica SBA-15 channel pores and were further used to initiate the RAFT polymerization of styrene and 4-vinylbenzyl azide, resulting in SBA-15 supported polystyrene-co-poly(4-vinylbenzyl azide) copolymer (PS-co-PVBA/SBA-15) hybrid material. The samples were characterized by Fourier transform infrared spectroscopy (FT-IR), transmission electron microscopy (TEM), thermogravimetry analysis (TGA), N₂ adsorption-desorption isotherms and X-ray diffraction (XRD), respectively. The results show that the styrene and 4-vinylbenzyl azide had copolymerized inside mesoporous silica SBA-15. Subsequently, Npropargyl-carbazole (PC) was connected to PS-co-PVBA/SBA-15 hybrid material via “click” reaction, resulting in PS-co-PVBC/SBA-15 with carbazole side groups hybrid material. The fluorescence spectrum is dominated by a broad band from 350 nm to 400 nm in narrow region and the maximum peak is 362 nm, indicating the characteristic absorption of the carbazole group of PS-co-PVBC/SBA-15 hybrid material.
- SBA-15,
- RAFT,
- “Click” chemistry,
- Fluorescence properties
1. [1]
  [1] O. Kir, W.H. Binder, Living anionic surface initiated polymerization (LASIP) of isoprene from silica nano-and glass particles, Eur. Polym. J. 49 (2013) 3078-3088.
2. [2]
  [2] L.P. Wang, Y.P. Wang, K. Yuan, Z.Q. Lei, Synthesis and characterization of surfaceinitiated polymer brushes on silicon substrates by reversible addition fragmentation chain transfer polymerization, Polym. Adv. Technol. 19 (2008) 285-290.
3. [3]
  [3] S. Berger, A. Synytska, L. Ionov, K.J. Eichhorn, M. Stamm, Stimuli-responsive bicomponent polymer janus particles by “grafting from”/“grafting to” approaches, Macromolecules 41 (2008) 9669-9676.
4. [4]
  [4] Q.S. Song, Y. Yang, K. Gao, H.H. Ma, Study on the novel rare-earth nanocrystals/PNIPAM complex hydrogels prepared by surface-initiated living radical polymerization, J. Lumin. 136 (2013) 437-443.
5. [5]
  [5] X.H. Lv, L.P. Wang, G. Li, et al., Preparation and characterization of optically functional hollow sphere hybrid materials by surface-initiated RATRP and “click” chemistry, Chin. Chem. Lett. 24 (2013) 335-337.
6. [6]
  [6] L.P. Wang, L.H. Dong, J.C. Hao, et al., Fabrication of block copolymer brushes on hollow sphere surface via reverse iodine transfer polymerization, J. Colloid Interface Sci. 361 (2011) 400-406.
7. [7]
  [7] J. Chen, M. Liu, C. Chen, H. Gong, C. Gao, Synthesis and characterization of silica nanoparticles with well-defined thermoresponsive PNIPAM via a combination of RAFT and click chemistry, ACS Appl. Mater. Interface 3 (2011) 3215-3223.
8. [8]
  [8] K. Jiang, C.N. Ye, P.P. Zhang, X.S. Wang, Y.L. Zhao, One-pot controlled synthesis of homopolymers and diblock copolymers grafted graphene oxide using couplable RAFT agents, Macromolecules 45 (2012) 1346-1355.
9. [9]
  [9] L.P. Wang, L.M. Zhao, W.Z. Li, Fabrication of polymer-hollow sphere opticalfunctional hybrid material via RAFT polymerization, React. Funct. Polym. 70 (2010) 35-40.
10. [10]
  [10] V. Subbaramaiah, V.C. Srivastava, I.D. Mall, Optimization of reaction parameters and kinetic modeling of catalytic wet peroxidation of picoline by Cu/SBA-15, Ind. Eng. Chem. Res. 52 (2013) 9021-9029.
11. [11]
  [11] K. Mantri, P.R. Selvakannan, J. Tardio, S.K. Bhargava, Synthesis of very high surface area Au-SBA-15 materials by confinement of gold nanoparticles formation within silica pore walls, Colloid Surf. A 429 (2013) 149-158.
12. [12]
  [12] P. Zarabadi-Poor, A. Badiei, A.A. Yousefi, J. Barroso-Flores, Selective optical sensing of Hg(Ⅱ) in aqueous media by H-acid/SBA-15: a combined experimental and theoretical study, J. Phys. Chem. C 117 (2013) 9281-9289.
13. [13]
  [13] J. Zhou, L. Wang, Q. Yang, et al., Novel thermoresponsive and pH-responsive aggregates from self-assembly of triblock copolymer PSMA-b-PNIPAAm-b-PSMA, J. Phys. Chem. B 111 (2007) 5573-5580.
14. [14]
  [14] J. Han, P. Fang, W. Jiang, L. Li, R. Guo, Ag-nanoparticle-loaded mesoporous silica: spontaneous formation of ag nanoparticles and mesoporous silica SBA-15 by a one-pot strategy and their catalytic applications, Langmuir 28 (2012) 4768-4775.
15. [15]
  [15] Y.P. Wang, X.W. Pei, X.Y. He, K. Yuan, Synthesis of well-defined, polymer-grafted silica nanoparticles via reverse ATRP, Eur. Polym. J. 41 (2005) 1326-1332.
16. [16]
  [16] K.Malagu, P.Gué rin, J.C.Guillemin, Preparationof solublepolymericsupportswith a functional group for liquid-phase organic synthesis, Synlett 2 (2002) 316-318.
17. [17]
  [17] C.H. Li, X.F. Liu,M.J. Yuan, et al., Unusual fluorescence enhancement of a novel carbazolyldiacetylene bound to gold nanoparticles, Langmuir 23 (2007) 6754-6760.
18. [18]
  [18] H. Zhao, W. Li, M. Du, X. Pu, X. Shao, A facile strategy to synthesize spherical SBA-15 silicas by the addition of poly(vinyl alcohol), Mater. Lett. 92 (2013) 33-35.
19. [19]
  [19] B.S. Tian, C. Yang, Temperature-responsive nanocomposites based on mesoporous SBA-15 silica and PNIPAAm: synthesis and characterization, J. Phys. Chem. C 113 (2009) 4925-4931.
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沈阳化工大学材料科学与工程学院沈阳 110142