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Citation: Xiao-Hong Miao, Song-De Han, Sui-Jun Liu, Xian-He Bu. Two lanthanide(III)-copper(II) chains based on [Cu2Ln2] clusters exhibiting high stability, magnetocaloric effect and slow magnetic relaxation[J]. Chinese Chemical Letters, ;2014, 25(6): 829-834. doi: 10.1016/j.cclet.2014.05.025 shu

Two lanthanide(III)-copper(II) chains based on [Cu2Ln2] clusters exhibiting high stability, magnetocaloric effect and slow magnetic relaxation

  • 1.

    Department of Chemistry and TKL of Metal-and Molecule-Based Material Chemistry, and Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Nankai University, Tianjin 300071, China

  • Corresponding author: Xian-He Bu, 
  • Received Date: 11 April 2014
    Available Online: 15 May 2014

    Fund Project:

  • Two 3d-4f heterometallic one-dimensional chains with neutral 4,4'-bipyridine ligands as linkers and [Cu2Ln2] clusters (Ln=Gd for 1, Dy for 2) as nodes have been hydrothermally synthesized and structurally characterized. Magnetic studies indicate that complex 1 exhibits a relatively large magnetocaloric effect, with an entropy change -△Smmax=24:8 J kg-1 K-1, whilst, complex 2 features slow magnetic relaxation at low temperature.
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