Citation: Rahmatollah Rahimi, Ali Maleki, Saied Maleki. Synthesis and characterization of a new magnetic bromochromate hybrid nanomaterial with triethylamine surface modified iron oxide nanoparticles[J]. Chinese Chemical Letters, ;2014, 25(6): 919-922. doi: 10.1016/j.cclet.2014.05.006 shu

Synthesis and characterization of a new magnetic bromochromate hybrid nanomaterial with triethylamine surface modified iron oxide nanoparticles

1.
Department of Chemistry, Iran University of Science and Technology, Tehran 16846-13114, Iran

Corresponding author: Ali Maleki,
Received Date: 7 February 2014
Available Online: 28 April 2014
Fund Project: The authors gratefully acknowledge financial support from the Iran National Science Foundation (INSF) (INSF)

We describe a novel method for the synthesis a new magnetic bromochromate hybrid nanomaterial, Fe₃O₄@SiO₂@TEA@[CrO₃Br], as a catalyst.Thephysical properties,morphology andmagnetic investigations of magnetic bromochromate hybrid nanomaterials are identified by transmission electron microscopy (TEM), scanning electronmicroscopy (SEM)and vibrating samplemagnetometer (VSM)techniques. Fourier transform infrared (FT-IR), elemental analysis, X-ray fluorescence (XRF), X-ray diffraction (XRD) were also used for structural identification. The quantity of chromiumis approximately 0.38%, which confirms to the immobilization amount of [CrO₃Br] and is equal to 0.007 mol/100 g.
- Magnetic nanoparticles,
- Fe₃O₄,
- Bromochromate
1. [1]
  [1] S.S. Mansoor, S.S. Shafi, Kinetics and mechanism of oxidation of aromatic aldehydes by imidazolium dichromate in aqueous acetic acid medium, Eur. J. Chem. 6 (2009) S522-S528.
2. [2]
  [2] S. Ghammamy, M.R. Baghy, W.W. Tak, et al., Synthesis, characterization X-ray structural analysis and study of oxidative properties of propyltriphenylphosphonium bromochromate, Trans. Metal. Chem. 32 (2007) 257-261.
3. [3]
  [3] F. Zamani, S.M. Hosseini, Palladium nanoparticles supported on Fe₃O₄/amino acid nanocomposite: highly active magnetic catalyst for solvent-free aerobic oxidation of alcohols, Catal. Commun. 43 (2014) 164-168.
4. [4]
  [4] F. Dehghani, A.R. Sardarian, M. Esmaeilpour, Salen complex of Cu(II) supported on superparamagnetic Fe₃O₄@SiO₂ nanoparticles: an efficient and recyclable catalyst for synthesis of 1-and 5-substituted 1H-tetrazoles, J. Organomet. Chem. 743 (2013) 87-96.
5. [5]
  [5] S.K. Li, X.C. Hou, F.Z. Huang, et al., Simple and efficient synthesis of copper(II)-modified uniform magnetic Fe₃O₄@SiO₂ core/shell microspheres for immobilization of cellulose, J. Nanopart. Res. 15 (2013) 1-12.
6. [6]
  [6] B. Rostami, B. Tahmasbi, H. Gholami, et al., Supported N-propylsulfamic acid on magnetic nanoparticles used as recoverableand recyclable catalyst for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones inwater,Chin.Chem.Lett.24(2013)211-214.
7. [7]
  [7] F. Nemati, R. Saeedirad, Nano-Fe₃O₄ encapsulated-silica particles bearing sulfonic acid groups as a magnetically separable catalyst for green and efficient synthesis of functionalized pyrimido [45-b] quinolines and indeno fused pyrido [2,3-d] pyrimidines in water, Chin. Chem. Lett. 24 (2013) 370-372.
8. [8]
  [8] K. Tabatabaeian, A.F. Shojaei, F. Shirini, S.Z. Hejazi, M. Rassa, A green multicomponent synthesis of bioactive pyrimido[4,5-b]quinoline derivatives as antibacterial agents in water catalyzed by RuCl₃•xH₂O, Chin. Chem. Lett. 25 (2014) 308-312.
9. [9]
  [9] A. Kleine, C.L. Altan, U.E. Yarar, et al., The polymerisation of oligo(ethylene glycol methyl ether) methacrylate from a multifunctional poly(ethyleneimine) derived amide: a stabiliser for the synthesis and dispersion of magnetite nanoparticles, Polym. Chem. 5 (2014) 524-534.
10. [10]
  [10] S. Wang, Z. Zhang, B. Liu, et al., Silica coated magnetic Fe₃O₄ nanoparticles supported phosphotungstic acid: a novel environment-friendly catalyst for the synthesis of 5-ethoxymethylfurfural from 5-hydroxymethylfurfural and fructose, Catal. Sci. Technol. 3 (2013) 2104-2112.
11. [11]
  [11] Z.P. Dong, X. Tian, Y.Z. Chen, Y.P. Guo, J.T. Ma, Dansyl derivative functionalized Fe₃O₄@SiO₂ fluorescent probe for detection and removal of Hg²⁺ in aqueous solution, RSC Adv. 3 (2013) 1082-1088.
12. [12]
  [12] F. Zhang, J. Jin, X. Zhong, et al., Pd immobilized on amine-functionalized magnetite nanoparticles: a novel and highly active catalyst for hydrogenation and Heck reactions, Green Chem. 13 (2011) 1238-1243.
13. [13]
  [13] Y. Long, Y. Chen, F. Yang, et al., Triphenylamine-functionalized magnetic microparticles as a new adsorbent coupled with high performance liquid chromatography for the analysis of trace polycyclic aromatic hydrocarbons in aqueous, Analyst 137 (2012) 2716-2722.
14. [14]
  [14] M.M. Farahani, J. Movassagh, F. Taghavi, P. Eghbali, F. Salimi, Magnetite-polyoxometalate hybrid nanomaterials: synthesis and characterization, Chem. Eng. J. 184 (2012) 342-346.
15. [15]
  [15] B. Chudasama, A.K. Vala, N. Andhariya, R.V. Upadhyay, R.V. Mehta, Enhanced antibacterial activity of bifunctional Fe₃O₄-Ag core-shell nanostructures, Nano. Res. 2 (2009) 955-965.
16. [16]
  [16] Z.P. Li, Y.Q. Wen, J.P. Shang, et al., Magnetically recoverable Cu₂O/Fe₃O₄ composite photocatalysts: fabrication and photocatalytic activity, Chin. Chem. Lett. 25 (2014) 287-291.
17. [17]
  [17] M.N. Esfahani, S.J. Hoseini, M. Montazerozohori, et al., Magnetic Fe₃O₄ nanoparticles: efficient and recoverable nanocatalyst for the synthesis of polyhydroquinolines and Hantzsch 1 4-dihydropyridines under solvent-free conditions, J. Mol. Catal. A: Chem. 382 (2014) 99-105.
18. [18]
  [18] H. Zhang, D.L. Liu, L.L. Zeng, et al., β-Cyclodextrin assisted one-pot synthesis of mesoporous magnetic Fe₃O₄@C and their excellent performance for the removal of Cr (VI) from aqueous solutions, Chin. Chem. Lett. 24 (2013) 341-343.
19. [19]
  [19] P. Modisha, T. Nyokong, E. Antunes, Photodegradation of Orange-G using zinc octacarboxyphthalocyanine supported on Fe₃O₄ nanoparticles, J. Mol. Catal. A: Chem. 380 (2013) 131-138.
20. [20]
  [20] N. Saadatjoo, M. Golshekan, S. Shariati, H. Kefayati, P. Azizi, Organic/inorganic MCM-41 magnetite nanocomposite as a solid acid catalyst for synthesis of benzo[α]xanthenone derivatives, J. Mol. Catal. A: Chem. 377 (2013) 173-179.
21. [21]
  [21] H. Yang, S. Li, X. Wang, et al., Core-shell silica magnetic microspheres supported proline as a recyclable organocatalyst for the asymmetric aldol reaction, J. Mol. Catal. A: Chem. 363-364 (2012) 404-410.
22. [22]
  [22] A. Maleki, Fe₃O₄/SiO₂ nanoparticles: an efficient and magnetically recoverable nanocatalyst for the one-pot multicomponent synthesis of diazepines, Tetrahedron 68 (2012) 7827-7833.
23. [23]
  [23] A. Maleki, One-pot multicomponent synthesis of diazepine derivatives using terminal alkynes in the presence of silica-supported superparamagnetic iron oxide nanoparticles, Tetrahedron Lett. 54 (2013) 2055-2059.
24. [24]
  [24] Y. Chi, Q. Yuan, Y.J. Li, et al., Synthesis of Fe₃O₄@SiO₂-Ag magnetic nanocomposite based on small-sized and highly dispersed silver nanoparticles for catalytic reduction of 4-nitrophenol, J. Colloid Interface Sci. 383 (2012) 96-102.
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沈阳化工大学材料科学与工程学院沈阳 110142