Citation: Fereshteh Karimian, Gholam Hossein Rounaghi, Mohammad Hossein Arbab-Zavar. Construction of a PVC based 15-crown-5 electrochemical sensor for Ag(I) cation[J]. Chinese Chemical Letters, ;2014, 25(05): 809-814. doi: 10.1016/j.cclet.2014.03.014 shu

Construction of a PVC based 15-crown-5 electrochemical sensor for Ag(I) cation

1.
Department of Chemistry, Faculty of Sciences, Ferdowsi University of Mashhad, Mashhad 9177948974, Iran

Corresponding author: Gholam Hossein Rounaghi,
Received Date: 29 July 2013
Available Online: 10 January 2014

The macrocyclic ligand, 15-crown-5, was used as an ionophore for fabrication of a polyvinyl chloride (PVC) based membrane sensor for Ag(I) cation. For construction of the Ag(I) cation selective electrode, the best response characteristics were obtained using the composition: 15-crown-5/PVC/o-nitrophenyloctylether (NPOE)/sodium tetraphenyl borate (NaTPB) in the percentage ratio of 5.6/30/60.5/3.9 (w/w/w/w). The electrochemical sensor shows a linear dynamic range 1.0×10^-7-1.0×10^-1 mol/L and a Nernstian slope of 58.9±0.5 mV/decade with a detection limit of 8.09×10^-8 mol/L for Ag(I) cation. It has a fast response time of <10 s and can be used for at least 8 weeks without any considerable divergences in its potential response. It was successfully used as an indicator electrode in potentiometric titration of Ag(I) cation with I^- and Cl^- anions and also for the determination of this metal cation in radiology waste water.
- 15-Crown-5,
- Electrochemical sensor,
- Potentiometry,
- Ag(I)
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