Citation: Chun-Lei Yang, Xu-Hai Zhang, Guo Lan, Lu-Yang Chen, Ming-Wei Chen, Yu-Qiao Zeng, Jian-Qing Jiang. Pd-based nanoporous metals for enzyme-free electrochemical glucose sensors[J]. Chinese Chemical Letters, ;2014, 25(4): 496-500. doi: 10.1016/j.cclet.2014.02.001
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Nanoporous metals (NPMs) show potential applications as enzyme-free glucose sensors. There are few reports on nanoporous Pd in this area even though their cost is much lower than other NPMs. In this work, we report the formation of Pd-based NPM with improved catalytic activity towards the oxidation of glucose. By dealloying metallic glasses, Pd-based NPMs with bi-continuous networks were obtained. All the Pd-based NPMs show high electrochemical catalytic activity towards glucose oxidation. In this study, NPM with an open, three-dimensional, ligament-channel nanoporous structure resulted by dealloying metallic Pd30Cu40Ni10P20, producing a pore size of 11 nm and a ligament size of 7 nm as the best configuration towards the direct oxidation reaction of glucose.
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Keywords:
- Glucose sensors,
- Pd-based NPM,
- Dealloying,
- Electrochemical
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[1]
[1] A. Heller, B. Feldman, Electrochemical glucose sensors and their applications in diabetes management, Chem. Rev. 108 (2008) 2482-2505.
-
[2]
[2] J. Wang, Electrochemical glucose biosensors, Chem. Rev. 108 (2008) 814-825.
-
[3]
[3] X.Y. Wang, S.Q. Liu, K.L. Huang, et al., Fixation of CO2 by electrocatalytic reduction to synthesis of dimethyl carbonate in ionic liquid using effective silver-coated nanoporous copper composites, Chin. Chem. Lett. 21 (2010) 987-990.
-
[4]
[4] S. Park, T.D. Chung, H.C. Kim, Nonenzymatic glucose detection using mesoporous platinum, Anal. Chem. 75 (2003) 3046-3049.
-
[5]
[5] J. Wang, D.F. Thomas, A. Chen, Nonenzymatic electrochemical glucose sensor based on nanoporous PtPb network, Anal. Chem. 80 (2003) 997-1004.
-
[6]
[6] S. Park, H. Boo, T.D. Chung, Electrochemical non-enzymatic glucose sensors, Anal. Chim. Acta 556 (2006) 46-57.
-
[7]
[7] C.X. Xu, Y.Q. Liu, F. Su, et al., Nanoporous PtAg and PtCu alloys with hollow ligament for enhanced electrocatalysis and glucose biosensing, Biosens. Bioelectron. 27 (2011) 160-166.
-
[8]
[8] D. van Noort, C.F. Mandenius, Porous gold surface for biosensor applications, Biosens Bioelectron. 15 (2000) 203-209.
-
[9]
[9] Z. Liu, L. Huang, L. Zhang, et al., Electrocatalytic oxidation of D-glucose at nanoporous Au and Au-Ag alloy electrodes in alkaline aqueous solutions, Electrochim. Acta 54 (2009) 7286-7293.
-
[10]
[10] Y. Ding, Y.J. Kim, J. Erlebacher, Nanoporous gold leaf: "Ancient technology"/advanced material, J. Adv. Mater. 16 (2004) 1897-1900.
-
[11]
[11] H.M. Yin, C.Q. Zhou, C. Xu, et al., Aerobic oxidation of D-glucose on support-free nanoporous gold, J. Phys. Chem. C 112 (2008) 9673-9678.
-
[12]
[12] N. Tavakkoli, S. Nasrollahi, Non-enzymatic glucose sensor based on palladium coated nanoporous gold film electrode, Aust. J. Chem. 66 (2013) 1097-1104.
-
[13]
[13] H.Y. Bai, M. Han, Y.Z. Du, et al., Facile synthesis of porous tubular palladium nanostructures and their application in a nonenzymatic glucose sensor, Chem. Commun. 46 (2010) 1739-1741.
-
[14]
[14] X. Chen, Z. Cai, Z. Lin, et al., A novel non-enzymatic ECL sensor for glucose using palladium nanoparticles supported on functional carbon nanotubes, Biosens Bioelectron. 24 (2009) 3475-3480.
-
[15]
[15] J. Erlebacher, An atomistic description of dealloying porosity evolution, the critical potential, and rate-limiting behavior, J. Electrochem. Soc. 151 (2004) C614-C626.
-
[16]
[16] J.L. Xu, Y. Wang, Z.H. Zhang, Potential and concentration dependent electrochemical dealloying of Al2Au in sodium chloride solutions, J. Phys. Chem. C 116 (2012) 5689-5699.
-
[17]
[17] J. Erlebacher, M.J. Aziz, A. Karma, et al., Evolution of nanoporosity in dealloying, Nature 410 (2001) 450-453.
-
[18]
[18] L.H. Qian, M.W. Chen, Ultrafine nanoporous gold by low temperature dealloying and kinetics of nanopore formation, Appl. Phys. Lett. 91 (2007) 083105-183105.
-
[19]
[19] Y. Kuang, B. Wu, D. Hu, et al., One-pot synthesis of highly dispersed palladium nanoparticles on acetylenic ionic liquid polymer functionalized carbon nanotubes for electrocatalytic oxidation of glucose, J. Solid State Electrochem. 16 (2012) 759-766.
-
[20]
[20] L.Y. Chen, X.Y. Lang, T. Fujita, et al., Nanoporous gold for enzyme-free electrochemical glucose sensors, Scr. Mater. 65 (2011) 17-20.
-
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