Citation: Yan Ma, Qian-Yun Tang, Ji Zhu, Li-Hong Wang, Cheng Yao. Fluorescent and thermal properties of siloxane-polyurethanes based on 1, 8-naphthalimide[J]. Chinese Chemical Letters, ;2014, 25(05): 680-686. doi: 10.1016/j.cclet.2014.01.048 shu

Fluorescent and thermal properties of siloxane-polyurethanes based on 1, 8-naphthalimide

1.
School of Science, Nanjing University of Technology, Nanjing 211816, China

Corresponding author: Cheng Yao,
Received Date: 16 December 2013
Available Online: 21 January 2014
Fund Project: Financial support from the 863 program (No. 2011AA02A204) is acknowledged. (No. 2011AA02A204)

A series of fluorescent siloxane-polyurethanes (HPMS-PUs) containing an amino-functionalized, 1,8-naphthalimide, fluorescent monomer (AABD) as a chain extender were synthesized. The properties of the HPMS-PUs were investigated by UV-vis and fluorescence spectroscopies, thermogravimetric analysis and thermal migration behavior. The maximum absorption and emission wavelengths of HPMS-PUs showed a red shift of about 4 nmand a blue shift of about 9 nm, respectively, compared to those of AABD. The Stokes shifts of AABD and HPMS-PU2 were 3514 and 2931 cm^-1, respectively. The quantum yield of HPMS-PU2 was 0.79, which was six times higher than that of AABD. Concentration self-quenching was observed in both AABD and HPMS-PUs. The fluorescence of HPMS-PUs was quite stable with respect to both temperature and fluorescence quencher effects. The thermal stability of HPMS-PUs increased with AABD content. The fluorophore units in the HPMS-PUs did not readily migrate.
- Polysiloxane,
- Polyurethane,
- 1,8-Naphthalimide,
- Fluorescence,
- Thermal properties
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沈阳化工大学材料科学与工程学院沈阳 110142