Citation: Yuan-Yuan Yao, Long Zhang, Zi-Fei Wang, Jing-Kun Xu, Yang-Ping Wen. Electrochemical determination of quercetin by self-assembled platinum nanoparticles/poly(hydroxymethylated-3,4-ethylenedioxylthiophene) nanocomposite modified glassy carbon electrode[J]. Chinese Chemical Letters, ;2014, 25(4): 505-510. doi: 10.1016/j.cclet.2014.01.028 shu

Electrochemical determination of quercetin by self-assembled platinum nanoparticles/poly(hydroxymethylated-3,4-ethylenedioxylthiophene) nanocomposite modified glassy carbon electrode

Yuan-Yuan Yao ^a,b ,
Long Zhang ^a ,
Zi-Fei Wang ^a,b ,
Jing-Kun Xu ^a,, ,
Yang-Ping Wen ^b,,

1.
a Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang 330013, China;
2.
b College of Science, Jiangxi Agricultural University, Nanchang 330045, China

Corresponding author: Jing-Kun Xu, Yang-Ping Wen,
Received Date: 24 October 2013
Available Online: 8 January 2014
Fund Project: Natural Science Foundation of Jiangxi Province (No. 2010GZH0041) (No. GJJ11590)Graduate Student Innovation Foundation of Jiangxi Province (No. YC2012-S123). (No. 2010GZH0041)

A simple and sensitive platinum nanoparticles/poly(hydroxymethylated-3,4-ethylenedioxylthiophene) nanocomposite (PtNPs/PEDOT-MeOH) modified glassy carbon electrode (GCE) was successfully developed for the electrochemical determination of quercetin. Scanning electron microscopy and energy dispersive X-ray spectroscopy results indicated that the PtNPs were inserted into the PEDOTMeOH layer. Compared with the bare GCE and poly(3,4-ethylenedioxythiophene) (PEDOT) electrodes, the PtNPs/PEDOT-MeOH/GCE modified electrode exhibited a higher electrocatalytic ability toward the oxidation of quercetin due to the synergic effects of the electrocatalytic activity and strong adsorption ability of PtNPs together with the good water solubility and high conductivity of PEDOT-MeOH. The electrochemical sensor can be applied to the quantification of quercetin with a linear range covering 0.04-91 μmol L^-1 and a low detection limit of 5.2 nmol L^-1. Furthermore, the modified electrode also exhibited good reproducibility and long-term stability, as well as high selectivity.
- Poly(3,4-ethylenedioxylthiophene,
- methanol),
- Platinum nanoparticles,
- Electropolymerization,
- Differential pulse voltammetry,
- Quercetin
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