Citation: Qing-Xiang Zhou, Yuan-Yuan Gao. Combination of ionic liquid dispersive liquid-phase microextraction and high performance liquid chromatography for the determination of triazine herbicides in water samples[J]. Chinese Chemical Letters, ;2014, 25(05): 745-748. doi: 10.1016/j.cclet.2014.01.026 shu

Combination of ionic liquid dispersive liquid-phase microextraction and high performance liquid chromatography for the determination of triazine herbicides in water samples

Qing-Xiang Zhou ^a,, ,
Yuan-Yuan Gao ^b

1.
a College of Geosciences, China University of Petroleum Beijing, Beijing 102249, China;
2.
b College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China

Corresponding author: Qing-Xiang Zhou,
Received Date: 16 December 2013
Available Online: 13 January 2014
Fund Project: This work was financially supported by the National Natural Science Foundation of China (No. 21377167) (No. 21377167) Program for New Century Excellent Talents in University (No. NCET-10-0813). (No. NCET-10-0813)

A temperature-controlled ionic liquid dispersive liquid-phasemicroextraction in combination with high performance liquid chromatography was developed for the enrichment and determination of triazine herbicides such as cyanazine, simazine, and atrazine in water samples. 1-Octyl-3-methylimidazolium hexafluorophosphate ([C₈MIM][PF₆]) was selected as the extraction solvent. Several experimental parameters were optimized. Under the optimal conditions, the linear range for cyanazine was in the concentration range of 0.5-80 μg/L and the linear range for simazine and atrazine was in the range of 1.0-100 mg/L. The limit of detection (LOD, S/N = 3) was in the ranges of 0.05-0.06 μg/L, and the intra day and inter day precision (RSDs, n = 6)was in the ranges of 3.2%-6.6% and 4.8%-8.9%, respectively. Four real water samples were analyzed with the developedmethod, and the experimental results showed that the spiked recoveries were satisfactory. All these exhibited that the developed method was a valuable tool for monitoring such pollutants.
- Temperature-controlled ionic liquid,
- dispersive liquid-phase microextraction,
- Ionic liquid,
- Triazine herbicides,
- High performance liquid chromatography
1. [1]
  [1] R.A. Boyd, Herbicides and herbicide degradates in shallow groundwater and the Cedar River near a municipal well field, Cedar Rapids, Iowa, Sci. Total Environ. 248 (2000) 241-253.
2. [2]
  [2] G. Shen, H.K. Lee, Determination of triazines in soil by microwave-assisted extraction followed by solid-phase microextraction and gas chromatography- mass spectrometry, J. Chromatogr. A 985 (2003) 167-174.
3. [3]
  [3] Y. Wang, J.Y. You, R.B. Ren, et al., Determination of triazines in honey by dispersive liquid-liquid microextraction high-performance liquid chromatography, J. Chromatogr. A 1217 (2010) 4241-4246.
4. [4]
  [4] Drinking Water Inspectorate, A report by the Chief Inspector, Drinking Water 1993, HMSO, London, 1994.
5. [5]
  [5] US Environmental Protection Agency, National Survey of Pesticides in Drinking Water Wells, Phase I Report, EPA PB-91-125765, National Technical Information Services, Springfield, VA, 1990.
6. [6]
  [6] EC Drinking Water Guideline, 98/83/CE, Brussels, November (1998).
7. [7]
  [7] C.L. Ye, Q.X. Zhou, X.M. Wang, Improved single-drop microextraction for high sensitive analysis, J. Chromatogr. A 1139 (2007) 7-13.
8. [8]
  [8] M. Rezaee, Y. Yamini, M. Faraji, Evolution of dispersive liquid-liquid microextraction method, J. Chromatogr. A 1217 (2010) 2342-2357.
9. [9]
  [9] R.S. Zhao, X. Wang, J.P. Yuan, S.S. Wang, C.G. Chen, Trace determination of hexabromocyclododecane diastereomers in water samples with temperature controlled ionic liquid dispersive liquid phase microextraction, Chin. Chem. Lett. 22 (2011) 883-886.
10. [10]
  [10] S. Wang, L. Ren, C.Y. Liu, J. Ge, F.M. Liu, Determination of five polar herbicides in water samples by ionic liquid dispersive liquid-phase microextraction, Anal. Bioanal. Chem. 397 (2010) 3089-3095.
11. [11]
  [11] Q.X. Zhou, H.H. Bai, G.H. Xie, J.P. Xiao, Temperature-controlled ionic liquid dispersive liquid phase micro-extraction, J. Chromatogr. A 1177 (2008) 43-49.
12. [12]
  [12] Q.X. Zhou, H.H. Bai, G.H. Xie, J.P. Xiao, Trace determination of organophosphorus pesticides in environmental samples by temperature-controlled ionic liquid dispersive liquid-phase microextraction, J. Chromatogr. A 1188 (2008) 148-153.
13. [13]
  [13] H.H. Bai, Q.X. Zhou, G.H. Xie, J.P. Xiao, Temperature-controlled ionic liquid-liquidphase microextraction for the pre-concentration of lead from environmental samples prior to flame atomic absorption spectrometry, Talanta 80 (2010) 1638-1642.
14. [14]
  [14] G. Cravotto, L. Boffa, J.M. Lévêque, et al., A speedy one-pot synthesis of secondgeneration ionic liquids under ultrasound and/or microwave, Aust. J. Chem. 60 (2007) 946-950.
1. [1]
  Tong Zhang , Xiaojing Liang , Licheng Wang , Shuai Wang , Xiaoxiao Liu , Yong Guo . An ionic liquid assisted hydrogel functionalized silica stationary phase for mixed-mode liquid chromatography. Chinese Chemical Letters, 2025, 36(1): 109889-. doi: 10.1016/j.cclet.2024.109889
2. [2]
  Jiajia Wang , XinXin Ge , Yajing Xiang , Xiaoliang Qi , Ying Li , Hangbin Xu , Erya Cai , Chaofan Zhang , Yulong Lan , Xiaojing Chen , Yizuo Shi , Zhangping Li , Jianliang Shen . An ionic liquid functionalized sericin hydrogel for drug-resistant bacteria-infected diabetic wound healing. Chinese Chemical Letters, 2025, 36(2): 109819-. doi: 10.1016/j.cclet.2024.109819
3. [3]
  Boyuan Hu , Jian Zhang , Yulin Yang , Yayu Dong , Jiaqi Wang , Wei Wang , Kaifeng Lin , Debin Xia . Dual-functional POM@IL complex modulate hole transport layer properties and interfacial charge dynamics for highly efficient and stable perovskite solar cells. Chinese Chemical Letters, 2024, 35(7): 108933-. doi: 10.1016/j.cclet.2023.108933
4. [4]
  Luyu Zhang , Zirong Dong , Shuai Yu , Guangyue Li , Weiwen Kong , Wenjuan Liu , Haisheng He , Yi Lu , Wei Wu , Jianping Qi . Ionic liquid-based in situ dynamically self-assembled cationic lipid nanocomplexes (CLNs) for enhanced intranasal siRNA delivery. Chinese Chemical Letters, 2024, 35(7): 109101-. doi: 10.1016/j.cclet.2023.109101
5. [5]
  Wangyan Hu , Ke Li , Xiangnan Dou , Ning Li , Xiayan Wang . Nano-sized stationary phase packings retained by single-particle frit for microchip liquid chromatography. Chinese Chemical Letters, 2024, 35(4): 108806-. doi: 10.1016/j.cclet.2023.108806
6. [6]
  Tian Feng , Yun-Ling Gao , Di Hu , Ke-Yu Yuan , Shu-Yi Gu , Yao-Hua Gu , Si-Yu Yu , Jun Xiong , Yu-Qi Feng , Jie Wang , Bi-Feng Yuan . Chronic sleep deprivation induces alterations in DNA and RNA modifications by liquid chromatography-mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(8): 109259-. doi: 10.1016/j.cclet.2023.109259
7. [7]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
8. [8]
  Feng-Qing Huang , Yu Wang , Ji-Wen Wang , Dai Yang , Shi-Lei Wang , Yuan-Ming Fan , Raphael N. Alolga , Lian-Wen Qi . Chemical isotope labeling-assisted liquid chromatography-mass spectrometry enables sensitive and accurate determination of dipeptides and tripeptides in complex biological samples. Chinese Chemical Letters, 2024, 35(11): 109670-. doi: 10.1016/j.cclet.2024.109670
9. [9]
  Jianwen Zhao , Shuai Wang , Shanshan Zhao , Liwei Chen , Fangang Meng , Xuelin Tian . A non-fluorinated liquid-like membrane with excellent anti-scaling performance for membrane distillation. Chinese Chemical Letters, 2025, 36(1): 109883-. doi: 10.1016/j.cclet.2024.109883
10. [10]
  Hongxia Li , Xiyang Wang , Du Qiao , Jiahao Li , Weiping Zhu , Honglin Li . Mechanism of nanoparticle aggregation in gas-liquid microfluidic mixing. Chinese Chemical Letters, 2024, 35(4): 108747-. doi: 10.1016/j.cclet.2023.108747
11. [11]
  Haoyang Wang , Ronghao Zhang , Yanlun Ren , Li Zhang . A convenient method for measuring gas-liquid volumetric mass transfer coefficient in micro reactors. Chinese Chemical Letters, 2024, 35(4): 108833-. doi: 10.1016/j.cclet.2023.108833
12. [12]
  Yang Li , Yihan Chen , Jiaxin Luo , Qihuan Li , Yiwu Quan , Yixiang Cheng . Enhanced circularly polarized luminescence emission promoted by achiral dichroic oligomers of F8BT in cholesteric liquid crystal. Chinese Chemical Letters, 2024, 35(11): 109864-. doi: 10.1016/j.cclet.2024.109864
13. [13]
  Yuqing Ding , Zhiying Yi , Zhihui Wang , Hongyu Chen , Yan Zhao . Liquid nitrogen post-treatment for improved aggregation and electrical properties in organic semiconductors. Chinese Chemical Letters, 2024, 35(12): 109918-. doi: 10.1016/j.cclet.2024.109918
14. [14]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
15. [15]
  Qiangwei Wang , Huijiao Liu , Mengjie Wang , Haojie Zhang , Jianda Xie , Xuanwei Hu , Shiming Zhou , Weitai Wu . Observation of high ionic conductivity of polyelectrolyte microgels in salt-free solutions. Chinese Chemical Letters, 2024, 35(4): 108743-. doi: 10.1016/j.cclet.2023.108743
16. [16]
  Haodong Wang , Xiaoxu Lai , Chi Chen , Pei Shi , Houzhao Wan , Hao Wang , Xingguang Chen , Dan Sun . Novel 2D bifunctional layered rare-earth hydroxides@GO catalyst as a functional interlayer for improved liquid-solid conversion of polysulfides in lithium-sulfur batteries. Chinese Chemical Letters, 2024, 35(5): 108473-. doi: 10.1016/j.cclet.2023.108473
17. [17]
  Wenhao Yan , Shuaiya Xue , Xuerui Zhao , Wei Zhang , Jian Li . Hexagonal boron nitride based slippery liquid infused porous surface with anti-corrosion, anti-contaminant and anti-icing properties for protecting magnesium alloy. Chinese Chemical Letters, 2024, 35(4): 109224-. doi: 10.1016/j.cclet.2023.109224
18. [18]
  Yufeng Wu , Mingjun Jing , Juan Li , Wenhui Deng , Mingguang Yi , Zhanpeng Chen , Meixia Yang , Jinyang Wu , Xinkai Xu , Yanson Bai , Xiaoqing Zou , Tianjing Wu , Xianyou Wang . Collaborative integration of Fe-N_x active center into defective sulfur/selenium-doped carbon for efficient oxygen electrocatalysts in liquid and flexible Zn-air batteries. Chinese Chemical Letters, 2024, 35(9): 109269-. doi: 10.1016/j.cclet.2023.109269
19. [19]
  Yixia Zhang , Caili Xue , Yunpeng Zhang , Qi Zhang , Kai Zhang , Yulin Liu , Zhaohui Shan , Wu Qiu , Gang Chen , Na Li , Hulin Zhang , Jiang Zhao , Da-Peng Yang . Cocktail effect of ionic patch driven by triboelectric nanogenerator for diabetic wound healing. Chinese Chemical Letters, 2024, 35(8): 109196-. doi: 10.1016/j.cclet.2023.109196
20. [20]
  Pei Cao , Yilan Wang , Lejian Yu , Miao Wang , Liming Zhao , Xu Hou . Dynamic asymmetric mechanical responsive carbon nanotube fiber for ionic logic gate. Chinese Chemical Letters, 2024, 35(6): 109421-. doi: 10.1016/j.cclet.2023.109421

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(659)
HTML views(26)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142