Citation: Cong-De Huo, Xia-Zhen Bao, Dong-Cheng Hu, Xiao-Dong Jia, Chou-Gu Sun, Cheng Wang. Triphenylphosphine-m-sulfonate/carbon tetrabromide as an easily recoverable catalyst system for the efficient synthesis of xanthene and xanthenone derivatives under solvent-free conditions[J]. Chinese Chemical Letters, ;2014, 25(05): 699-701. doi: 10.1016/j.cclet.2014.01.023
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A solid complex, readily prepared from commercially available sodium triphenylphosphine-m-sulfonate (TPPMS) and carbon tetrabromide, can be used as an easily recoverable and reusable catalyst system for one-pot condensation of 2-naphthol with aldehydes to construct 14-aryl(alkyl)-14H-dibenzo[a,j]- xanthene derivatives and one-pot condensation of 2-naphthol with aldehydes and cyclic 1,3-dicarbonyl compounds to construct 12-aryl(alkyl)-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one derivatives.
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Keywords:
- Xanthene,
- Xanthenone,
- Naphthol,
- Aldehyde
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