Citation: Cong-De Huo, Xia-Zhen Bao, Dong-Cheng Hu, Xiao-Dong Jia, Chou-Gu Sun, Cheng Wang. Triphenylphosphine-m-sulfonate/carbon tetrabromide as an easily recoverable catalyst system for the efficient synthesis of xanthene and xanthenone derivatives under solvent-free conditions[J]. Chinese Chemical Letters, ;2014, 25(05): 699-701. doi: 10.1016/j.cclet.2014.01.023 shu

Triphenylphosphine-m-sulfonate/carbon tetrabromide as an easily recoverable catalyst system for the efficient synthesis of xanthene and xanthenone derivatives under solvent-free conditions

  • Corresponding author: Cong-De Huo, 
  • Received Date: 11 November 2013
    Available Online: 2 January 2014

    Fund Project: We thank the National Natural Science Foundation of China (Nos. 21002080, 21262029) (Nos. 21002080, 21262029)the Specialized Research Fund for the Doctoral Program of Higher Education (No. 20106203120003) of the Education Ministry for financially supporting this work. (No. 20106203120003)

  • A solid complex, readily prepared from commercially available sodium triphenylphosphine-m-sulfonate (TPPMS) and carbon tetrabromide, can be used as an easily recoverable and reusable catalyst system for one-pot condensation of 2-naphthol with aldehydes to construct 14-aryl(alkyl)-14H-dibenzo[a,j]- xanthene derivatives and one-pot condensation of 2-naphthol with aldehydes and cyclic 1,3-dicarbonyl compounds to construct 12-aryl(alkyl)-8,9,10,12-tetrahydrobenzo[a]xanthen-11-one derivatives.
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