Citation: Tan-Yu Cheng, Jing-Lan Zhuang, Hui Yao, Huai-Sheng Zhang, Guo-Hua Liu. Immobilization of chiral Rh catalyst on glass and application to asymmetric transfer hydrogenation of aryl ketones in aqueous media[J]. Chinese Chemical Letters, ;2014, 25(4): 613-616. doi: 10.1016/j.cclet.2014.01.007 shu

Immobilization of chiral Rh catalyst on glass and application to asymmetric transfer hydrogenation of aryl ketones in aqueous media

1.
Key Laboratory of Resource Chemistry of Ministry of Education, College of Life and Environmental Science, Shanghai Normal University, Shanghai 200234, China

Corresponding author: Tan-Yu Cheng, Guo-Hua Liu,
Received Date: 7 October 2013
Available Online: 24 December 2013

A chiral catalyst, Cp^*RhTsDPEN (Cp^* = pentamethyl cyclopentadiene, TsDPEN = substitutive phenylsulfonyl-1,2-diphenylethylenediamine), was synthesized and immobilized at the surface of glass. The immobilized catalyst exhibited good catalytic efficiency for asymmetric transfer hydrogenation of aromatic ketones in water with HCOONa as hydrogen source.
- Heterogeneous Rh catalyst,
- Asymmetric transfer hydrogenation,
- Aromatic ketones,
- Glass substrate
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沈阳化工大学材料科学与工程学院沈阳 110142