Citation: Shu Hong Li, Liang Chun Li, Cai Hong Xu. Synthesis and crystal structure of polyaryl substituted diene derivatives based on the reduction of diphenylacetylene with lithium naphthalenide[J]. Chinese Chemical Letters, ;2012, 23(1): 69-72. doi: 10.1016/j.cclet.2011.10.009 shu

Synthesis and crystal structure of polyaryl substituted diene derivatives based on the reduction of diphenylacetylene with lithium naphthalenide

a Department of Chemistry, School of Science, Beijing Technology and Business University, Beijing 100048, China;
b Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China

Received Date: 7 July 2011

Fund Project: The authors gratefully acknowledge the National Science Foundation of China (Nos. 50673094 and 20774102) for financial support.

The reduction of diphenylacetylene with lithium naphthalenide produced two kinds of intermediates, 1 or 2, depending on the ratio of diphenylacetylene to lithium naphthalenide. A series of polyaryl substituted ethylene/diene derivatives were synthesized by reaction of electrophiles with the corresponding intermediates produced in-situ. All new compounds were fully characterized, and their single crystal structures were determined.
- Lithium naphthalenide,
- Reduction,
- Diphenylacetylene,
- Diene derivatives
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