Citation: Jian Xun Wang, Kung Tung Chen, Shiuh Tsuen Huang, Chiing Chang Chen. Application of Li₂SiO₃ as a heterogeneous catalyst in the production of biodiesel from soybean oil[J]. Chinese Chemical Letters, ;2011, 22(11): 1363-1366. doi: 10.1016/j.cclet.2011.05.041 shu

Application of Li₂SiO₃ as a heterogeneous catalyst in the production of biodiesel from soybean oil

a Department of Science Application and Dissemination, National Taichung University of Education, Taichung 40306, Taiwan;
b The Teaching Center of Natural Science, Minghsin University of Science and Technology, Hsinchu 30401, Taiwan

Received Date: 28 March 2011

Biodiesel was synthesized from soybean oil by transesterification over Li₂SiO₃ catalyst. The Li₂SiO₃ can be used for biodiesel production directly without further drying or thermal pretreatment, no obvious difference in the FAME conversion (92.4-96.7%) between the air-exposed catalyst (24-72 h) and the fresh one (94.2%). This leads to important benefits when considering industrial applications of Li₂SiO₃ as a solid catalyst for storing and handling catalyst without taking special actions.
- Biodiesel,
- Solid catalyst,
- Li₂SiO₃,
- Transesterification,
- Triglyceride
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19. [19]
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20. [20]
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