Citation: Shen Luan Yu, Yan Yun Li, Zhen Rong Dong, Juan Ni Zhang, Qi Li, Jing Xing Gao. Synthesis of novel chiral N, P-containing multidentate ligands and their applications in asymmetric transfer hydrogenation[J]. Chinese Chemical Letters, ;2011, 22(11): 1269-1272. doi: 10.1016/j.cclet.2011.05.033 shu

Synthesis of novel chiral N, P-containing multidentate ligands and their applications in asymmetric transfer hydrogenation

State Key Laboratory of Physical Chemistry of Solid Surfaces, National Engineering Laboratory for Green Chemical Productions of Alcohols-Ethers-Esters and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Received Date: 16 February 2011

Fund Project: The authors are grateful to the National Natural Science Foundation of China (Nos.20423002 and 20703034), Natural Science Foundation of Fujian Province of China (No.2008J0235) for the financial support of this work.

Novel chiral PN₄-type multidentate aminophosphine ligands have been successfully synthesized by Schiff-base condensation of bis(o-formylphenyl)phenylphosphane and various chiral amino-sulfonamides. Their structures were fully characterized by IR, EI-MS and NMR. The catalytic systems, prepared in situ from the multidentate ligands and iridium(I) complexes, showed high activity in asymmetric transfer hydrogenation of propiophenone in 2-propanol solution, leading to corresponding optical alcohol with up to 75% ee.
- Chiral multidentate aminophosphine ligand,
- Indium complex,
- Propiophenone,
- Asymmetric transfer hydrogenation
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