Citation: Zong Fan Duan, Zhi Gang Yang, Dong Jie Liu, Li Cai, Daiki Hoshino, Tsuyoshi Morita, Gao Yang Zhao, Yasushiro Nishioka. Facile synthesis and characterization of a novel thiophene-fused polycyclic aromatics based on pyrene[J]. Chinese Chemical Letters, ;2011, 22(7): 819-822. doi: 10.1016/j.cclet.2010.12.054 shu

Facile synthesis and characterization of a novel thiophene-fused polycyclic aromatics based on pyrene

a College of Science and Technology, Nihon University, Narashinodai, Funabashi, Chiba 2748501, Japan;
b School of Materials Science & Engineering, Xi’an University of Technology, Xi’an 710048, China;
c College of Pharmacy, Nihon University, Narashinodai, Funabashi, Chiba 2748555, Japan

Received Date: 28 October 2010

A novel large thiophene-fused polycyclic aromatics 1 based on pyrene 5 has been synthesized, and its structure was confirmed by 1H NMR, ^13>C NMR, MS, UV–vis and elemental analysis. The key steps of the synthesis involved the Stille cross-coupling reaction and followed by selective β-β oxidative cyclization of pendant thienyl rings by FeCl₃ under mild conditions.
- Pyrene,
- Thiophene,
- Stille coupling reaction,
- Oxidative cyclization
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