Citation: Lig Fang Zha, Wei Sen Yang, Wen Yan Hao, Ming Zhong Cai. Hydrosilylation of olefins over rhodium complex anchored over thioether-functionalized MCM-41[J]. Chinese Chemical Letters, ;2010, 21(11): 1310-1313. doi: 10.1016/j.cclet.2010.06.007 shu

Hydrosilylation of olefins over rhodium complex anchored over thioether-functionalized MCM-41

Department of Chemistry, Jiangxi Normal University, Nanchang 330022, China

Received Date: 17 March 2010

Fund Project: We thank the National Natural Science Foundation of China (No.20862008) and Natural Science Foundation of Jiangxi Province (No.2008GQH0034) for financial support.

The hydrosilylation of alkenes with triethoxysilane has been achieved at 120℃ in the presence of 0.01 mol% of thioether-functionalized MCM-41 anchored rhodium complex, affording the corresponding addition products in 68-91% yields. This supported rhodium complex can be reused several times without noticeable loss of activity. Our system not only solves the basic problems of catalyst separation and recovery, hat also avoids the use of phosphine ligands.
- Supported rhodium catalyst,
- Sulfur rhodium complex,
- Hydrosilylation,
- MCM-41,
- Heterogeneous catalysis
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