Citation: Hiroaki Matsuoka, Kazuhiro Kondo. Metal-free catalytic reduction of aldehydes,ketones,aldimines,and ketimines[J]. Chinese Chemical Letters, ;2010, 21(11): 1314-1317. doi: 10.1016/j.cclet.2010.05.029 shu

Metal-free catalytic reduction of aldehydes,ketones,aldimines,and ketimines

Hiroaki Matsuoka ^a, ,
Kazuhiro Kondo ^a,b

a Graduate School of Medical Sciences, Nagoya City University, Nagoya 467-8601, Japan;
b Graduate School of Pharmaceutical Sciences, Nagoya City University, Nagoya 467-8603, Japan

Received Date: 18 March 2010

The metal-free combination of catalytic amounts of PPh₃, B(C₆F₅)₃, and PhSiH₃ can efficiently hydrosilylate aldehydes, ketones, aldimines and ketimines to afford the corresponding reduction products in good yields.
- Metal-free hydrosilylation,
- Reduction,
- Ketone,
- Ketimine
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