Citation: Ardeshir Khazaei, Amin Rostami, Fatemeh Mantashlo. p-Toluenesulfonyl chloride as a new and effective catalyst for acetylation and formylation of hydroxyl compounds under mild conditions[J]. Chinese Chemical Letters, ;2010, 21(12): 1430-1434. doi: 10.1016/j.cclet.2010.05.025 shu

p-Toluenesulfonyl chloride as a new and effective catalyst for acetylation and formylation of hydroxyl compounds under mild conditions

a Faculty of Chemistry, Bu-Ali Sina University, Hamedan 6517838683, Iran;
b Department of Chemistry, Faculty of Science, University of Kurdistan, Sanandaj 66135, Iran

Received Date: 15 April 2010

The catalytic application of p-toluenesulfonyl chloride for efficient acetylation of various types of alcohols and phenols with acetic anhydride in solvent-free conditions is reported. Also structurally diverse alcohols were formylated using formic acid based on the use of catalytic amount of p-toluenesulfonyl chloride under solvent-free condition. The reactions were carried out in short reaction time and in good to excellent yields at room temperature.
- p-Toluenesulfonyl chloride,
- Hydroxyl compounds,
- Acetylation,
- Formylation
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