Citation: Qing Min Zhang, Chuang Chen, Hong Xia Zhang, Chun Qing Zhang, Yang Li, Xi Gao Jian. Synthesis and characterization of star-comb styrene/butadiene copolymer[J]. Chinese Chemical Letters, ;2010, 21(11): 1370-1373. doi: 10.1016/j.cclet.2010.05.013 shu

Synthesis and characterization of star-comb styrene/butadiene copolymer

Qing Min Zhang ^a, ,
Chuang Chen ^a,b ,
Hong Xia Zhang ^a,b ,
Chun Qing Zhang ^a,b ,
Yang Li ^a,b ,
Xi Gao Jian ^a,b

a State Key Laboratory of Fine Chemicals, Department of Polymer Science and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116012, China;
b Liaoning Province Key Laboratory of Polymer Science and Engineering, Dalian 116012, China

Received Date: 15 March 2010

Fund Project: This work was financially supported by the National High Technology Research and Development Program of China (No.2007AA03Z532), the National Natural Science Foundation of China (No.20774015), and the China National Petroleum Corporation Innovation Fund (No.07E1034).

A novel star-comb styrene/butadiene copolymer (SC-SBC) was synthesized by anionic polymerization and grafting reaction with epoxidized star liquid polybutadiene (ESPB) as coupling agent. The overall shape of the star-comb macromolecules can be altered by changing the molecular weight and number of the side chain. The molecular parameters and mechanical properties of the SC-SBC resins were investigated. The notched izod impact strength of the SC-SBC resins are excellent and reach as high as to 239 J/m.
- Anionic polymerization,
- Epoxidation,
- Grafting reaction,
- Star-comb eopolymer,
- Side chain
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