Citation: Rui Bao, Min Pan, Jin Jun Qiu, He Qing Tang, Cheng Mei Liu. Photo-polymerization of liquid crystalline monomer in oriented liquid crystal phase[J]. Chinese Chemical Letters, ;2010, 21(11): 1330-1333. doi: 10.1016/j.cclet.2010.05.010 shu

Photo-polymerization of liquid crystalline monomer in oriented liquid crystal phase

School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Received Date: 1 March 2010

Fund Project: The authors are grateful to NSF of China (No.50703013) and Independent Innovative Position of Hubei Province for financial support of this work.We appreciate the experimental support from Professor D.K.Yang.

A new approach to synthesize liquid crystalline polymer with narrow polydispersity index (PDI) was developed. Photo-polymerization of 4-cyanophenyl-4'-(6-acryloyloxyhexyloxy) benzoate(RM23)in nematic liquid crystals with macroscopic orientation was studied. The effects of the monomer concentration on the molecular weight and PDI of the resulting polymers were studied through gel permeation chromatography(GPC)and polarized optical microscopy. The low PDI of 1.19 and 1.22 was obtained in the reverse and normal modes, respectively. The PDI and molecular weight increased with monomer concentration.
- Photo-polymerization,
- 4-Cyanophenyl-4'-(6-acryloyloxyhexyloxy) benzoate,
- Liquid crystal,
- Macroscopic orientation,
- Synthesis
1. [1]
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