Citation: Jia Fen Zhou, Xuan Chen, Qing Bing Wang, Bo Zhang, Li Yan Zhang, Abdullah Yusulf, Zhong Fu Wang, Jian Bo Zhang, Jie Tang. H₂SO_4--SiO₂:Highly efficient and novel catalyst for the Ferrier-type glycosylation[J]. Chinese Chemical Letters, ;2010, 21(8): 922-926. doi: 10.1016/j.cclet.2010.03.013 shu

H₂SO_4--SiO₂:Highly efficient and novel catalyst for the Ferrier-type glycosylation

a Department of Chemistry, East China Normal University, Shanghai 200062, China;
b School of Life Sciences, Northwestern University, Xi'an 710069, China

Received Date: 4 December 2009

Fund Project: We thank the analytic center of East China Normal University for data measurement. The project was supported by Shanghai Rising-Star Program (No. 06QA14018) and University Students Innovative Activities Project of Shanghai Municipal Education Commission (No. KY2008-09S).

Sulfuric acid immobilized on silica gel is designed as a very useful catalyst for synthesis of 2,3-unsaturated glycopyranosides.This handy,metal-free,environment friendly transformation provides high yields and α-stereoselectivities in a very few amount (< 0.02 eq.=of catalyst and in short reaction times (< 10 min).
- Glycosylation,
- H₂SO_4--SiO₂,
- Ferrier rearrangement,
- O-glycosides
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