Citation: Zhen Ting Du, Hong Rui Yu, Yan Xu, Yong Li, An Pai Li. Synthesis of bisabolane sesquiterpenes:A Johnson-Claisen rearrangement approach[J]. Chinese Chemical Letters, ;2010, 21(7): 813-815. doi: 10.1016/j.cclet.2010.02.024 shu

Synthesis of bisabolane sesquiterpenes:A Johnson-Claisen rearrangement approach

Zhen Ting Du ^a, ,
Hong Rui Yu ^a ,
Yan Xu ^a ,
Yong Li ^a ,
An Pai Li ^b

a Northwest A & F University, College of Science, Yangling 712100, China;
b Synthetics Technologica Pte Ltd., 3 Phillip Street, #18-00 Commerce Point 048693, Singapore

Received Date: 25 November 2009

Fund Project: Financial support from Program for Excellent Young Talents in Northwest A&F University (No. 2111020712) as well as the National Natural Science Foundation of China (No. 20802058) is greatly appreciated.

sSeveral bisabolane sesquiterpenes, (±)-curcumene, (±)-curcuphenol, (±)-curcudiol and (±)-curcuhydroquinone, have been synthesized in racemic form and fully characterized. The salient characteristic of our approach is that a Johnson-Claisen arrangement was involved as a key step.
- Bisabolane sesquiterpenes,
- Johnson-Claisen rearrangement,
- Synthesis
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