Citation: Hai Tao Xi, Tian Tian Yi, Xiao Qiang Sun. The synthesis, characterization and X-ray diffractometry structure of fluorine-containing cyclobis (paraquat-p-phenylene) tetracation[J]. Chinese Chemical Letters, ;2010, 21(6): 633-636. doi: 10.1016/j.cclet.2010.01.028 shu

The synthesis, characterization and X-ray diffractometry structure of fluorine-containing cyclobis (paraquat-p-phenylene) tetracation

Key Laboratory of Fine Petrochemical Engineering, Jiangsu Polytechnic University, Changzhou 213164, China

Received Date: 3 November 2009

Fund Project: We acknowledge financial support from the National Natural Science Foundation of China (No. 20872051).

Two novel fluorine-containing cyclophanes 1 and 2 incorporating a 1,4-bismethylfluorophenylene subunits have been synthesized via the template-directed clipping methodology and their structure was characterized by ¹H NMR, ¹³C NMR, MALDI-TOF-MS and elemental analysis. X-ray diffraction analysis of the solid state molecular structure showed that the complex units are linked by non-classical C-H…F hydrogen bonding.
- Fluorine-cotiaining cyclophanes,
- 1,4-Bis (bromomethyl)-2-fluorobenzene,
- Crystal structure,
- Synthesis
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