Citation: Xue Yu Tao, Wen Feng Qiu, Hao Li, Tong Zhao. One pot synthesis of a soluble polymer for zirconium carbide[J]. Chinese Chemical Letters, ;2010, 21(5): 620-623. doi: 10.1016/j.cclet.2010.01.002 shu

One pot synthesis of a soluble polymer for zirconium carbide

Xue Yu Tao ^a,b, ,
Wen Feng Qiu ^a ,
Hao Li ^a ,
Tong Zhao ^a

a Laboratory of Advanced Polymer Materials, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
b Graduate School of Chinese Academy of Sciences, Beijing 100049, China

Received Date: 6 November 2009

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 50702057) and the Natural Science Foundation of Zhanjiang Normal University (No. L0604).

A new polymer, polyzirconoxanesal (PZS), is synthesized from the reaction of zirconium oxychloride octahydrate (ZrOCl₂·8H₂O) with acetylacetone (Hacac) and salicyl alcohol (SA) by one-pot protocol. The polymer is soluble in common organic solvents, such as ethanol, methanol, acetone, tetrahydrofuran and chloroform, and exhibits rheology with viscosity of 100-300 mpa s at 25℃. These properties are suitable for uses in fabrication of ceramic matrix fiber composites. Pyrolysis of this polymer at 1300℃ in argon provides nanosized ZrC with spherical morphology and size of 20-100 nm.
- Zirconium carbide,
- Preceramic polymer,
- Morphology
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