Citation: Xiao Quan Lu, Jun Ying Ma, Xiu Hui Liu, Cun Wu Dong, Wen Ting Wang. Kinetic comparison between ferric ion and decamethyferrocene at the liquid/liquid interface as studied by scanning electrochemical microscopy[J]. Chinese Chemical Letters, ;2010, 21(1): 89-92. doi: 10.1016/j.cclet.2009.08.014 shu

Kinetic comparison between ferric ion and decamethyferrocene at the liquid/liquid interface as studied by scanning electrochemical microscopy

College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China

Received Date: 21 May 2009

Fund Project: This work was supported by the National Natural Science Foundation of China (No. 20875077, No. 20775060 and No. 20927004), the Natural Science Foundation of Gansu (No. 0701RJZA109 and No. 0803RJZA105) and Key Projects of Scientific Research Base of Department of Education, Gansu Province (No. 08zx-07).

Comparison in electron transfer (ET) processes from decamethyferrocene (DMFe) in nitrobenzene (NB) to ferric ion in aqueous phase was investigated for the first time by the scanning electrochemical microscopy (SECM). As compared with the system of Fe(CN)₆^3--DMFe, the ET rate obtained from Fe³⁺-DMFe was lower in spite of larger driving force, which may arise from the effect of reorganization energy. Otherwise, the effect of common ion on rate constants was also probed and results suggested additional complexity of the ET mechanism between Fe(CN)₆^3-and DMFe.
- SECM,
- Electron transfer(ET),
- Liquid/liquid interface(L/L),
- Reorganization energy
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