Citation: Chuan Zhou Tao, Wei Wei Liu, Ji You Sun. Copper-catalyzed synthesis of phenols from aryl halides and 4-methoxylbenzyl alcohol[J]. Chinese Chemical Letters, ;2009, 20(10): 1170-1174. doi: 10.1016/j.cclet.2009.06.004 shu

Copper-catalyzed synthesis of phenols from aryl halides and 4-methoxylbenzyl alcohol

a Department of Chemical Engineering, Huaihai Institute of Technology, Lianyungang 222005, China;
b Jiangsu Marine Resources R & D Institute, Lianyungang 222005, China

Received Date: 5 March 2009

Fund Project: We are grateful to the Six Kinds of Professional Elite Foundation of Jiangsu Province (No.07-A-024)the Natural Science Foundation of Jiangsu Education Department (No.08KJB150002) and the Natural Science Foundation of Huaihai Institute of Technology (No.Z2008024) for financial support.

A catalytic method was developed to synthesize substituted phenols from the corresponding aryl bromides and chlorides under mild conditions (yields=34-92%).4-Methoxylbenzyl alcohol was used as water surrogate and CuI/3,4,7,8-tetramethyl-1,10-phenanthroline was used as catalyst to achieve the C-O cross-coupling.
- Copper catalysis,
- Water surrogate,
- Cross-coupling,
- Phenols
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