Citation: Jin Ping Song, Yu Jing Guo, Shao Min Shuang, Chuan Dong. Study on the supramolecular systems of two basic violets with cyclodextrins by MWNTs/Nafion modified glassy carbon electrode[J]. Chinese Chemical Letters, ;2009, 20(8): 981-984. doi: 10.1016/j.cclet.2009.03.018 shu

Study on the supramolecular systems of two basic violets with cyclodextrins by MWNTs/Nafion modified glassy carbon electrode

a Research Center for Environmental Science and Engineering, Shanxi University, Taiyuan 030006, China;
b Medical College of Shanxi Datong University, Datong 037000, China

Received Date: 3 December 2008

Fund Project: This work was supported by the National Natural Science Foundation of China (No.90813018) and the Natural Science Foundation of Shanxi Province of China (No.2007011023).

The electrochemical properties of two basic violets (methyl violet and ethyl violet) at the MWNTs/Nafion modified glassy carbon electrode were investigated. The redox of the basic violets is two-electron and two-proton process, and methyl violet presents stronger electron transfer capacity than ethyl violet. Meanwhile, the inclusion constants of the two basic violets with five CDs were determined by differential pulse voltammetry (DPV). The two basic violets and CDs can form 1:1 complexes.The inclusion capacities of the two basic violets follow the same order:CM-β-CD > HP-β-CD > TM-β-CD > DM-β-CD > β-CD.
- Basic violet,
- Carbon nanotubes,
- Modified electrode,
- Inclusion complexes
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