Citation: Lin Fang Shi, Bin Li, Li Ying Zhang. A bright blue emission material based on anthracene:Synthesis,characterization and luminescent properties[J]. Chinese Chemical Letters, ;2009, 20(9): 1047-1050. doi: 10.1016/j.cclet.2009.03.017 shu

A bright blue emission material based on anthracene:Synthesis,characterization and luminescent properties

Lin Fang Shi ^a,b, ,
Bin Li ^a ,
Li Ying Zhang ^a,b

a Key Laboratory of Excited State Processes, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, China;
b Graduate School of the Chinese Academy of Sciences, Chinese Academy of Sciences, Beijing 100039, China

Received Date: 22 December 2008

Fund Project: The authors gratefully thank the financial supports of One Hundred Talents Project from the Chinese Academy of Sciences and the NSFC (No.50872130).

A blue light-emitting material, 2-(N-ethyl-anthraceneyl-9) imidazo [4,5-f] 1,10-phenanthroline (EAIP), has been synthesized and characterized by ¹H NMR, IR, elemental and single crystal X-ray diffraction analysis. The results of theoretical calculations indicate that the HOMO and LUMO distributions mainly locate at the anthracene fragment. It displays bright blue emission in both solid state and dichloromethane solution. The emission quantum yield calculated is 0.76.
- Crystal structure,
- X-ray diffraction,
- Luminescence
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