Citation: Yu Bo Jiang, Chun Xiang Kuang. Convenient one-pot synthesis of functionalized (E)-2-arylvinyl bromides from (E)-4-(2-bromovinyl)phenyl acetate[J]. Chinese Chemical Letters, ;2009, 20(5): 545-548. doi: 10.1016/j.cclet.2009.01.020 shu

Convenient one-pot synthesis of functionalized (E)-2-arylvinyl bromides from (E)-4-(2-bromovinyl)phenyl acetate

Department of Chemistry, Tongji University, Siping Road 1239, Shanghai 200092, China

Received Date: 15 October 2008

Fund Project: The work was supported by the Natural Science Foundation of Shanghai, China (No.06ZR14085) and by the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry.We would like to thank the Center for Instrumental Analysis, Tongji University, China.

A convenient one-pot synthesis of functionalized (E)-2-arylvinyl bromides was achieved by microwave-induced deacetylation and subsequent acylation using dicyclohexyl carbodiimide (DCC) and dimethylamino-pyridine (DMAP) at room temperature from (E)-4-(2-bromovinyl)phenyl acetate.
- One-pot synthesis,
- (E)-2-Arylvinyl bromide,
- Acylation,
- Deacetylation
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