Citation: Shao Yong Li, Bei Sun, Zhi Chao Xiao, Ming Hui Huang, Wei Xue Xie, Jun Min Liu. One-step synthesis of inherently chiral p-tert-butylcalix[4]azacrown[J]. Chinese Chemical Letters, ;2009, 20(6): 640-642. doi: 10.1016/j.cclet.2009.01.019 shu

One-step synthesis of inherently chiral p-tert-butylcalix[4]azacrown

a College of Pharmacy, Tianjin Medical University, Tianjin 300070, China;
b School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China

Received Date: 10 November 2008

Fund Project: We thank the Science Foundation of Tianjin Medical University (No.2006x9d2) and the National Natural Science Foundation of China, the Major State Basic Research Development Program of China (No.20502008) for financial support.

A one-step procedure is developed to synthesize inherently chiral p-tert-butylcalix[4]azacrown 1 through etherification between p-tert-butylcalix[4]arene and compound 3, which can be amplified to efficiently prepare more inherently chiral calix[4]arenes in ABHH substitution pattern.
- Calix[4]arene,
- Inherently chiral,
- One-step
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