Citation: Xiao Ning Wei, Ling Yan Liu, Bing Wang, Wei Xing Chang, Jing Li. In(OTf)₃ catalyzed allylation reaction of imines with tetraallyltin[J]. Chinese Chemical Letters, ;2009, 20(1): 40-43. doi: 10.1016/j.cclet.2008.10.013 shu

In(OTf)₃ catalyzed allylation reaction of imines with tetraallyltin

The State Key Laboratory Elemento-Organic Chemistry, Institute of Elemento-Organic Chemistry, Nankai University, Tanjin 300071, China

Received Date: 26 June 2008

Fund Project: We are grateful to the National Natural Science Foundation of China (Nos. 20421202, 20372033) for financial support.

In the presence of catalytic amount of In(OTf)₃ (10 mol%), a series of aldimines reacted with tetraallyltin in a 2:1 molar ratio to afford the corresponding homoallylic amines in good yields. The good atom efficiency was achieved under mild reaction conditions and a new protocol (allyl)₄Sn/In(OTf)₃ for simple imines was developed.
- Catalytic allylation,
- Aldimine,
- Tetraallyltin,
- In(OTf)₃
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